Methane adsorption and methanol desorption of copper modified boron silicate

Boron silicate (BS) with a chabazite framework structure was synthesised using a direct route and rigorously characterized before it was ion-exchanged with copper to form Cu-BS. Employing in situ infrared spectroscopy, we show that Cu-BS is capable of oxidising methane to methoxy species and methano...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Xueting, Shishkin, Alexander, Hemmingsson, Felix, Skoglundh, Magnus, Martinez-Casado, Francisco Javier, Bock, Lorenz, Idström, Alexander, Nordstierna, Lars, Härelind, Hanna, Carlsson, Per-Anders
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9088827/
https://www.ncbi.nlm.nih.gov/pubmed/35558450
http://dx.doi.org/10.1039/c8ra08038k
_version_ 1784704392808628224
author Wang, Xueting
Shishkin, Alexander
Hemmingsson, Felix
Skoglundh, Magnus
Martinez-Casado, Francisco Javier
Bock, Lorenz
Idström, Alexander
Nordstierna, Lars
Härelind, Hanna
Carlsson, Per-Anders
author_facet Wang, Xueting
Shishkin, Alexander
Hemmingsson, Felix
Skoglundh, Magnus
Martinez-Casado, Francisco Javier
Bock, Lorenz
Idström, Alexander
Nordstierna, Lars
Härelind, Hanna
Carlsson, Per-Anders
author_sort Wang, Xueting
collection PubMed
description Boron silicate (BS) with a chabazite framework structure was synthesised using a direct route and rigorously characterized before it was ion-exchanged with copper to form Cu-BS. Employing in situ infrared spectroscopy, we show that Cu-BS is capable of oxidising methane to methoxy species and methanol interacts with the boron sites without deprotonation.
format Online
Article
Text
id pubmed-9088827
institution National Center for Biotechnology Information
language English
publishDate 2018
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-90888272022-05-11 Methane adsorption and methanol desorption of copper modified boron silicate Wang, Xueting Shishkin, Alexander Hemmingsson, Felix Skoglundh, Magnus Martinez-Casado, Francisco Javier Bock, Lorenz Idström, Alexander Nordstierna, Lars Härelind, Hanna Carlsson, Per-Anders RSC Adv Chemistry Boron silicate (BS) with a chabazite framework structure was synthesised using a direct route and rigorously characterized before it was ion-exchanged with copper to form Cu-BS. Employing in situ infrared spectroscopy, we show that Cu-BS is capable of oxidising methane to methoxy species and methanol interacts with the boron sites without deprotonation. The Royal Society of Chemistry 2018-10-26 /pmc/articles/PMC9088827/ /pubmed/35558450 http://dx.doi.org/10.1039/c8ra08038k Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Wang, Xueting
Shishkin, Alexander
Hemmingsson, Felix
Skoglundh, Magnus
Martinez-Casado, Francisco Javier
Bock, Lorenz
Idström, Alexander
Nordstierna, Lars
Härelind, Hanna
Carlsson, Per-Anders
Methane adsorption and methanol desorption of copper modified boron silicate
title Methane adsorption and methanol desorption of copper modified boron silicate
title_full Methane adsorption and methanol desorption of copper modified boron silicate
title_fullStr Methane adsorption and methanol desorption of copper modified boron silicate
title_full_unstemmed Methane adsorption and methanol desorption of copper modified boron silicate
title_short Methane adsorption and methanol desorption of copper modified boron silicate
title_sort methane adsorption and methanol desorption of copper modified boron silicate
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9088827/
https://www.ncbi.nlm.nih.gov/pubmed/35558450
http://dx.doi.org/10.1039/c8ra08038k
work_keys_str_mv AT wangxueting methaneadsorptionandmethanoldesorptionofcoppermodifiedboronsilicate
AT shishkinalexander methaneadsorptionandmethanoldesorptionofcoppermodifiedboronsilicate
AT hemmingssonfelix methaneadsorptionandmethanoldesorptionofcoppermodifiedboronsilicate
AT skoglundhmagnus methaneadsorptionandmethanoldesorptionofcoppermodifiedboronsilicate
AT martinezcasadofranciscojavier methaneadsorptionandmethanoldesorptionofcoppermodifiedboronsilicate
AT bocklorenz methaneadsorptionandmethanoldesorptionofcoppermodifiedboronsilicate
AT idstromalexander methaneadsorptionandmethanoldesorptionofcoppermodifiedboronsilicate
AT nordstiernalars methaneadsorptionandmethanoldesorptionofcoppermodifiedboronsilicate
AT harelindhanna methaneadsorptionandmethanoldesorptionofcoppermodifiedboronsilicate
AT carlssonperanders methaneadsorptionandmethanoldesorptionofcoppermodifiedboronsilicate

Ejemplares similares