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One step synthesis of high-efficiency AgBr–Br–g-C(3)N(4) composite catalysts for photocatalytic H(2)O(2) production via two channel pathway

In this work, a two-component modified AgBr–Br–g-C(3)N(4) composite catalyst with outstanding photocatalytic H(2)O(2) production ability is synthesized. XRD, UV-Vis, N(2) adsorption, TEM, XPS, EPR and PL were used to characterize the obtained catalysts. The as-prepared AgBr–Br–g-C(3)N(4) composite c...

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Detalles Bibliográficos
Autores principales: Wang, Yunke, Hu, Shaozheng, Li, Qiang, Gu, Guizhou, Zhao, Yanfeng, Liang, Hongyu, Li, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9088936/
https://www.ncbi.nlm.nih.gov/pubmed/35558951
http://dx.doi.org/10.1039/c8ra07749e
Descripción
Sumario:In this work, a two-component modified AgBr–Br–g-C(3)N(4) composite catalyst with outstanding photocatalytic H(2)O(2) production ability is synthesized. XRD, UV-Vis, N(2) adsorption, TEM, XPS, EPR and PL were used to characterize the obtained catalysts. The as-prepared AgBr–Br–g-C(3)N(4) composite catalyst shows the highest H(2)O(2) equilibrium concentration of 3.9 mmol L(−1), which is 7.8 and 19.5 times higher than that of GCN and AgBr. A “two channel pathway” is proposed for this reaction system which causes the remarkably promoted H(2)O(2) production ability. In addition, compared with another two-component modified catalyst, Ag–AgBr–g-C(3)N(4), AgBr–Br–g-C(3)N(4) composite catalyst displays the higher photocatalytic H(2)O(2) production ability and stability.