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An efficient nickel/silver co-catalyzed remote C–H amination of 8-aminoquinolines with azodicarboxylates at room temperature
A highly efficient nickel/silver co-catalyzed C–H amination at the C5 position of 8-aminoquinolines with azodicarboxylates at room temperature is reported. The reaction undergoes a self-redox process without the necessity of external oxidant. It proceeded under simple and mild conditions without any...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9088955/ https://www.ncbi.nlm.nih.gov/pubmed/35557799 http://dx.doi.org/10.1039/c8ra07647b |
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author | Zhao, Ruinan Yang, Yaocheng Wang, Xia Ren, Peng Zhang, Qian Li, Dong |
author_facet | Zhao, Ruinan Yang, Yaocheng Wang, Xia Ren, Peng Zhang, Qian Li, Dong |
author_sort | Zhao, Ruinan |
collection | PubMed |
description | A highly efficient nickel/silver co-catalyzed C–H amination at the C5 position of 8-aminoquinolines with azodicarboxylates at room temperature is reported. The reaction undergoes a self-redox process without the necessity of external oxidant. It proceeded under simple and mild conditions without any additional ligand, base or oxidant and provided the desired products in good to excellent yields. This method also possessed the merits of good functional group compatibility and air and moisture tolerance. It provides an efficient strategy for the synthesis of useful quinoline derivatives. |
format | Online Article Text |
id | pubmed-9088955 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90889552022-05-11 An efficient nickel/silver co-catalyzed remote C–H amination of 8-aminoquinolines with azodicarboxylates at room temperature Zhao, Ruinan Yang, Yaocheng Wang, Xia Ren, Peng Zhang, Qian Li, Dong RSC Adv Chemistry A highly efficient nickel/silver co-catalyzed C–H amination at the C5 position of 8-aminoquinolines with azodicarboxylates at room temperature is reported. The reaction undergoes a self-redox process without the necessity of external oxidant. It proceeded under simple and mild conditions without any additional ligand, base or oxidant and provided the desired products in good to excellent yields. This method also possessed the merits of good functional group compatibility and air and moisture tolerance. It provides an efficient strategy for the synthesis of useful quinoline derivatives. The Royal Society of Chemistry 2018-11-05 /pmc/articles/PMC9088955/ /pubmed/35557799 http://dx.doi.org/10.1039/c8ra07647b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Zhao, Ruinan Yang, Yaocheng Wang, Xia Ren, Peng Zhang, Qian Li, Dong An efficient nickel/silver co-catalyzed remote C–H amination of 8-aminoquinolines with azodicarboxylates at room temperature |
title | An efficient nickel/silver co-catalyzed remote C–H amination of 8-aminoquinolines with azodicarboxylates at room temperature |
title_full | An efficient nickel/silver co-catalyzed remote C–H amination of 8-aminoquinolines with azodicarboxylates at room temperature |
title_fullStr | An efficient nickel/silver co-catalyzed remote C–H amination of 8-aminoquinolines with azodicarboxylates at room temperature |
title_full_unstemmed | An efficient nickel/silver co-catalyzed remote C–H amination of 8-aminoquinolines with azodicarboxylates at room temperature |
title_short | An efficient nickel/silver co-catalyzed remote C–H amination of 8-aminoquinolines with azodicarboxylates at room temperature |
title_sort | efficient nickel/silver co-catalyzed remote c–h amination of 8-aminoquinolines with azodicarboxylates at room temperature |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9088955/ https://www.ncbi.nlm.nih.gov/pubmed/35557799 http://dx.doi.org/10.1039/c8ra07647b |
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