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Electroreduction of CO(2) and Quantification in New Transition-Metal-Based Deep Eutectic Solvents Using Single-Atom Ag Electrocatalyst

[Image: see text] Deep eutectic solvents (DESs) are efficient media for CO(2) capture, and an electroreduction process using the deterministic surface of single-atom electrocatalysts is a facile way to screen gas absorption capacities of novel DESs. Using newly prepared transition-metal-based DESs i...

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Autores principales: Halilu, Ahmed, Hadj-Kali, Mohamed K., Hashim, Mohd Ali, Ali, Emad M., Bhargava, Suresh K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9089364/
https://www.ncbi.nlm.nih.gov/pubmed/35559187
http://dx.doi.org/10.1021/acsomega.2c00672
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author Halilu, Ahmed
Hadj-Kali, Mohamed K.
Hashim, Mohd Ali
Ali, Emad M.
Bhargava, Suresh K.
author_facet Halilu, Ahmed
Hadj-Kali, Mohamed K.
Hashim, Mohd Ali
Ali, Emad M.
Bhargava, Suresh K.
author_sort Halilu, Ahmed
collection PubMed
description [Image: see text] Deep eutectic solvents (DESs) are efficient media for CO(2) capture, and an electroreduction process using the deterministic surface of single-atom electrocatalysts is a facile way to screen gas absorption capacities of novel DESs. Using newly prepared transition-metal-based DESs indexed as TDESs, the interfacial mechanism, detection, quantification, and coordination modes of CO(2) were determined for the first time. The CO(2) has a minimum detection time of 300 s, whereas 500 s of continous ambient CO(2) saturation provided ZnCl(2)/ethanolamine (EA) (1:4) and CoCl(2)/EA (1:4) TDESs with a maximum CO(2) absorption capacity of 0.2259 and 0.1440 mmol/L, respectively. The results indicated that CO(2) coordination modes of η(1) (C) and η(2) (O, O) with Zn in ZnCl(2)/EA (1:4) TDESs are conceivable. We found that the transition metals in TDESs form an interface at the compact layer of the electrocatalyst, while CO(2)(•–)/CO(2) reside in the diffuse layer. These findings are important because they provide reliable inferences about interfacial phenomena for facile screening of CO(2) capture capacity of DESs or other green solvents.
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spelling pubmed-90893642022-05-11 Electroreduction of CO(2) and Quantification in New Transition-Metal-Based Deep Eutectic Solvents Using Single-Atom Ag Electrocatalyst Halilu, Ahmed Hadj-Kali, Mohamed K. Hashim, Mohd Ali Ali, Emad M. Bhargava, Suresh K. ACS Omega [Image: see text] Deep eutectic solvents (DESs) are efficient media for CO(2) capture, and an electroreduction process using the deterministic surface of single-atom electrocatalysts is a facile way to screen gas absorption capacities of novel DESs. Using newly prepared transition-metal-based DESs indexed as TDESs, the interfacial mechanism, detection, quantification, and coordination modes of CO(2) were determined for the first time. The CO(2) has a minimum detection time of 300 s, whereas 500 s of continous ambient CO(2) saturation provided ZnCl(2)/ethanolamine (EA) (1:4) and CoCl(2)/EA (1:4) TDESs with a maximum CO(2) absorption capacity of 0.2259 and 0.1440 mmol/L, respectively. The results indicated that CO(2) coordination modes of η(1) (C) and η(2) (O, O) with Zn in ZnCl(2)/EA (1:4) TDESs are conceivable. We found that the transition metals in TDESs form an interface at the compact layer of the electrocatalyst, while CO(2)(•–)/CO(2) reside in the diffuse layer. These findings are important because they provide reliable inferences about interfacial phenomena for facile screening of CO(2) capture capacity of DESs or other green solvents. American Chemical Society 2022-04-18 /pmc/articles/PMC9089364/ /pubmed/35559187 http://dx.doi.org/10.1021/acsomega.2c00672 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Halilu, Ahmed
Hadj-Kali, Mohamed K.
Hashim, Mohd Ali
Ali, Emad M.
Bhargava, Suresh K.
Electroreduction of CO(2) and Quantification in New Transition-Metal-Based Deep Eutectic Solvents Using Single-Atom Ag Electrocatalyst
title Electroreduction of CO(2) and Quantification in New Transition-Metal-Based Deep Eutectic Solvents Using Single-Atom Ag Electrocatalyst
title_full Electroreduction of CO(2) and Quantification in New Transition-Metal-Based Deep Eutectic Solvents Using Single-Atom Ag Electrocatalyst
title_fullStr Electroreduction of CO(2) and Quantification in New Transition-Metal-Based Deep Eutectic Solvents Using Single-Atom Ag Electrocatalyst
title_full_unstemmed Electroreduction of CO(2) and Quantification in New Transition-Metal-Based Deep Eutectic Solvents Using Single-Atom Ag Electrocatalyst
title_short Electroreduction of CO(2) and Quantification in New Transition-Metal-Based Deep Eutectic Solvents Using Single-Atom Ag Electrocatalyst
title_sort electroreduction of co(2) and quantification in new transition-metal-based deep eutectic solvents using single-atom ag electrocatalyst
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9089364/
https://www.ncbi.nlm.nih.gov/pubmed/35559187
http://dx.doi.org/10.1021/acsomega.2c00672
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