Micro-flow nanocatalysis: synergic effect of TfOH@SPIONs and micro-flow technology as an efficient and robust catalytic system for the synthesis of plasticizers

The combination of continuous flow technology with immobilizing of only 0.13 mol% of triflic acid (TfOH) on silica-encapsulated superparamagnetic iron oxide nanoparticles (SPIONs) under solvent-free conditions successfully provided a powerful, efficient, and eco-friendly route for the synthesis of p...

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Autores principales: Tashi, Maryam, Shafiee, Behnaz, Sakamaki, Yoshie, Hu, Ji-Yun, Heidrick, Zachary, Khosropour, Ahmad R., Beyzavi, M. Hassan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9089408/
https://www.ncbi.nlm.nih.gov/pubmed/35558628
http://dx.doi.org/10.1039/c8ra07838f
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author Tashi, Maryam
Shafiee, Behnaz
Sakamaki, Yoshie
Hu, Ji-Yun
Heidrick, Zachary
Khosropour, Ahmad R.
Beyzavi, M. Hassan
author_facet Tashi, Maryam
Shafiee, Behnaz
Sakamaki, Yoshie
Hu, Ji-Yun
Heidrick, Zachary
Khosropour, Ahmad R.
Beyzavi, M. Hassan
author_sort Tashi, Maryam
collection PubMed
description The combination of continuous flow technology with immobilizing of only 0.13 mol% of triflic acid (TfOH) on silica-encapsulated superparamagnetic iron oxide nanoparticles (SPIONs) under solvent-free conditions successfully provided a powerful, efficient, and eco-friendly route for the synthesis of plasticizers. The turnover frequency value in micro-flow conditions varied in the range of 948.7 to 7384.6 h(−1) compared to 403.8 to 3099 h(−1) for in-flask. This technique works efficiently, encouraging future applications of micro-flow nano-catalysis in green chemistry.
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spelling pubmed-90894082022-05-11 Micro-flow nanocatalysis: synergic effect of TfOH@SPIONs and micro-flow technology as an efficient and robust catalytic system for the synthesis of plasticizers Tashi, Maryam Shafiee, Behnaz Sakamaki, Yoshie Hu, Ji-Yun Heidrick, Zachary Khosropour, Ahmad R. Beyzavi, M. Hassan RSC Adv Chemistry The combination of continuous flow technology with immobilizing of only 0.13 mol% of triflic acid (TfOH) on silica-encapsulated superparamagnetic iron oxide nanoparticles (SPIONs) under solvent-free conditions successfully provided a powerful, efficient, and eco-friendly route for the synthesis of plasticizers. The turnover frequency value in micro-flow conditions varied in the range of 948.7 to 7384.6 h(−1) compared to 403.8 to 3099 h(−1) for in-flask. This technique works efficiently, encouraging future applications of micro-flow nano-catalysis in green chemistry. The Royal Society of Chemistry 2018-11-13 /pmc/articles/PMC9089408/ /pubmed/35558628 http://dx.doi.org/10.1039/c8ra07838f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Tashi, Maryam
Shafiee, Behnaz
Sakamaki, Yoshie
Hu, Ji-Yun
Heidrick, Zachary
Khosropour, Ahmad R.
Beyzavi, M. Hassan
Micro-flow nanocatalysis: synergic effect of TfOH@SPIONs and micro-flow technology as an efficient and robust catalytic system for the synthesis of plasticizers
title Micro-flow nanocatalysis: synergic effect of TfOH@SPIONs and micro-flow technology as an efficient and robust catalytic system for the synthesis of plasticizers
title_full Micro-flow nanocatalysis: synergic effect of TfOH@SPIONs and micro-flow technology as an efficient and robust catalytic system for the synthesis of plasticizers
title_fullStr Micro-flow nanocatalysis: synergic effect of TfOH@SPIONs and micro-flow technology as an efficient and robust catalytic system for the synthesis of plasticizers
title_full_unstemmed Micro-flow nanocatalysis: synergic effect of TfOH@SPIONs and micro-flow technology as an efficient and robust catalytic system for the synthesis of plasticizers
title_short Micro-flow nanocatalysis: synergic effect of TfOH@SPIONs and micro-flow technology as an efficient and robust catalytic system for the synthesis of plasticizers
title_sort micro-flow nanocatalysis: synergic effect of tfoh@spions and micro-flow technology as an efficient and robust catalytic system for the synthesis of plasticizers
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9089408/
https://www.ncbi.nlm.nih.gov/pubmed/35558628
http://dx.doi.org/10.1039/c8ra07838f
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