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Understanding Complex Electron Radiolysis in Saline Solution by Big Data Analysis

[Image: see text] In this article, we developed a new method to analyze the complex chemical reactions induced by electron beam radiolysis based on big data analysis. At first, we built an element transport network to show the chemical reactions. Furthermore, the linearity between the species was qu...

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Autores principales: Zhang, Zhihao, Guo, Hongxuan, Liu, Bo, Xian, Dali, Liu, Xuanxuan, Da, Bo, Sun, Litao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9089687/
https://www.ncbi.nlm.nih.gov/pubmed/35572744
http://dx.doi.org/10.1021/acsomega.2c01010
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author Zhang, Zhihao
Guo, Hongxuan
Liu, Bo
Xian, Dali
Liu, Xuanxuan
Da, Bo
Sun, Litao
author_facet Zhang, Zhihao
Guo, Hongxuan
Liu, Bo
Xian, Dali
Liu, Xuanxuan
Da, Bo
Sun, Litao
author_sort Zhang, Zhihao
collection PubMed
description [Image: see text] In this article, we developed a new method to analyze the complex chemical reactions induced by electron beam radiolysis based on big data analysis. At first, we built an element transport network to show the chemical reactions. Furthermore, the linearity between the species was quantified by Pearson correlation coefficient analysis. Based on the analysis, the mechanism of the high linearity between the special species pairs was interpreted by the element transport roadmap and chemical equations. The time variation of the pH of the solution and bubble formation in the solution were analyzed by simulation and data analysis. The simulation indicates that O(2) and H(2) can easily oversaturate and form bubbles. Finally, the radiolysis of high-energy electrons in pure water was analyzed as a reference for the radiolysis of high-energy electrons in saline solution. This work provides a new method for investigating a high-energy electron radiolysis process and for simplifying a complex chemical reaction based on quantitative analysis of the species variation in the reaction.
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spelling pubmed-90896872022-05-12 Understanding Complex Electron Radiolysis in Saline Solution by Big Data Analysis Zhang, Zhihao Guo, Hongxuan Liu, Bo Xian, Dali Liu, Xuanxuan Da, Bo Sun, Litao ACS Omega [Image: see text] In this article, we developed a new method to analyze the complex chemical reactions induced by electron beam radiolysis based on big data analysis. At first, we built an element transport network to show the chemical reactions. Furthermore, the linearity between the species was quantified by Pearson correlation coefficient analysis. Based on the analysis, the mechanism of the high linearity between the special species pairs was interpreted by the element transport roadmap and chemical equations. The time variation of the pH of the solution and bubble formation in the solution were analyzed by simulation and data analysis. The simulation indicates that O(2) and H(2) can easily oversaturate and form bubbles. Finally, the radiolysis of high-energy electrons in pure water was analyzed as a reference for the radiolysis of high-energy electrons in saline solution. This work provides a new method for investigating a high-energy electron radiolysis process and for simplifying a complex chemical reaction based on quantitative analysis of the species variation in the reaction. American Chemical Society 2022-04-21 /pmc/articles/PMC9089687/ /pubmed/35572744 http://dx.doi.org/10.1021/acsomega.2c01010 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Zhang, Zhihao
Guo, Hongxuan
Liu, Bo
Xian, Dali
Liu, Xuanxuan
Da, Bo
Sun, Litao
Understanding Complex Electron Radiolysis in Saline Solution by Big Data Analysis
title Understanding Complex Electron Radiolysis in Saline Solution by Big Data Analysis
title_full Understanding Complex Electron Radiolysis in Saline Solution by Big Data Analysis
title_fullStr Understanding Complex Electron Radiolysis in Saline Solution by Big Data Analysis
title_full_unstemmed Understanding Complex Electron Radiolysis in Saline Solution by Big Data Analysis
title_short Understanding Complex Electron Radiolysis in Saline Solution by Big Data Analysis
title_sort understanding complex electron radiolysis in saline solution by big data analysis
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9089687/
https://www.ncbi.nlm.nih.gov/pubmed/35572744
http://dx.doi.org/10.1021/acsomega.2c01010
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