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Pressure-Induced Structural Phase Transition in EuNi(2)P(2)
[Image: see text] EuNi(2)P(2) was studied with a diamond anvil cell (DAC) and X-ray diffraction (XRD). The structural evolution of powder crystal EuNi(2)P(2) under high pressure up to 137 GPa and its single-crystal structure up to 9 GPa were reported. The unique structural phase transition of this 1...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9089697/ https://www.ncbi.nlm.nih.gov/pubmed/35572745 http://dx.doi.org/10.1021/acsomega.2c01325 |
Sumario: | [Image: see text] EuNi(2)P(2) was studied with a diamond anvil cell (DAC) and X-ray diffraction (XRD). The structural evolution of powder crystal EuNi(2)P(2) under high pressure up to 137 GPa and its single-crystal structure up to 9 GPa were reported. The unique structural phase transition of this 122-type crystal occurred above 70 GPa in powder crystal EuNi(2)P(2). The diffraction data from single-crystal EuNi(2)P(2) revealed the coordinate change of the P atom, and the stability of the crystal at 9 GPa was confirmed. The crystal EuNi(2)P(2) remained stable with a tetragonal phase without obvious symmetry changes during compression to 137 GPa. |
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