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Photoinduced Trifluoromethylation with CF(3)Br as a Trifluoromethyl Source: Synthesis of α-CF(3)-Substituted Ketones

[Image: see text] An efficient and novel photoinduced trifluoromethylation employing CF(3)Br as a trifluoromethyl source is described. With commercially accessible fac-Ir((III))(ppy)(3) as the catalyst, radical trifluoromethylation between O-silyl enol ether and CF(3)Br occurs successfully. This met...

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Detalles Bibliográficos
Autores principales:	Ma, Ransong, Deng, Zhoubin, Wang, Ke-Hu, Wang, Junjiao, Huang, Danfeng, Su, Yingpeng, Hu, Yulai, Lv, Xiaobo
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9089747/ https://www.ncbi.nlm.nih.gov/pubmed/35573213 http://dx.doi.org/10.1021/acsomega.2c01241

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