Metal free oxidation of vinamidine derivatives: a simple synthesis of α-keto-β-diimine ligands

Oxidation of vinamidinium salts with meta-chloroperbenzoic acid is the key synthetic step towards new persistent 1,3-di(amino)oxyallyl radical cations. When applied to parent vinamidines, this protocol allows for a simple straightforward synthesis of α-keto-β-diimine ligands, for which no convenient...

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Autores principales: Tripathi, Monika, Regnier, Vianney, Ziani, Zakaria, Devillard, Marc, Philouze, Christian, Martin, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9089801/
https://www.ncbi.nlm.nih.gov/pubmed/35559111
http://dx.doi.org/10.1039/c8ra08220k
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author Tripathi, Monika
Regnier, Vianney
Ziani, Zakaria
Devillard, Marc
Philouze, Christian
Martin, David
author_facet Tripathi, Monika
Regnier, Vianney
Ziani, Zakaria
Devillard, Marc
Philouze, Christian
Martin, David
author_sort Tripathi, Monika
collection PubMed
description Oxidation of vinamidinium salts with meta-chloroperbenzoic acid is the key synthetic step towards new persistent 1,3-di(amino)oxyallyl radical cations. When applied to parent vinamidines, this protocol allows for a simple straightforward synthesis of α-keto-β-diimine ligands, for which no convenient synthesis was previously available.
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spelling pubmed-90898012022-05-11 Metal free oxidation of vinamidine derivatives: a simple synthesis of α-keto-β-diimine ligands Tripathi, Monika Regnier, Vianney Ziani, Zakaria Devillard, Marc Philouze, Christian Martin, David RSC Adv Chemistry Oxidation of vinamidinium salts with meta-chloroperbenzoic acid is the key synthetic step towards new persistent 1,3-di(amino)oxyallyl radical cations. When applied to parent vinamidines, this protocol allows for a simple straightforward synthesis of α-keto-β-diimine ligands, for which no convenient synthesis was previously available. The Royal Society of Chemistry 2018-11-14 /pmc/articles/PMC9089801/ /pubmed/35559111 http://dx.doi.org/10.1039/c8ra08220k Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Tripathi, Monika
Regnier, Vianney
Ziani, Zakaria
Devillard, Marc
Philouze, Christian
Martin, David
Metal free oxidation of vinamidine derivatives: a simple synthesis of α-keto-β-diimine ligands
title Metal free oxidation of vinamidine derivatives: a simple synthesis of α-keto-β-diimine ligands
title_full Metal free oxidation of vinamidine derivatives: a simple synthesis of α-keto-β-diimine ligands
title_fullStr Metal free oxidation of vinamidine derivatives: a simple synthesis of α-keto-β-diimine ligands
title_full_unstemmed Metal free oxidation of vinamidine derivatives: a simple synthesis of α-keto-β-diimine ligands
title_short Metal free oxidation of vinamidine derivatives: a simple synthesis of α-keto-β-diimine ligands
title_sort metal free oxidation of vinamidine derivatives: a simple synthesis of α-keto-β-diimine ligands
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9089801/
https://www.ncbi.nlm.nih.gov/pubmed/35559111
http://dx.doi.org/10.1039/c8ra08220k
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