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Quantitative syntheses of permethylated closo-1,10-R(2)C(2)B(8)Me(8) (R = H, Me) carboranes. Egg-shaped hydrocarbons on the Frontier between inorganic and organic chemistry
Electrophilic methylation of the closo-1,10-R(2)C(2)B(8)H(8) (1) (R = H or Me) dicarbaboranes at higher temperatures or thermal rearrangement of the 1,6-R(2)C(2)B(8)Me(8) (3) compounds at 400–500 °C generated the B-permethylated derivatives closo-1,10-R(2)C(2)B(8)Me(8) (2) in quantitative (>95%)...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9090134/ https://www.ncbi.nlm.nih.gov/pubmed/35559069 http://dx.doi.org/10.1039/c8ra06640j |