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Understanding the effects of vicinal carbon substituents and configuration on organofluorine hydrogen-bonding interaction
An investigation of C–F⋯H–O hydrogen bonds in the complexes CH(n)XCH(n)F⋯H(2)O (n = 0, 1, 2; X = H, F, Cl, Br) was performed at the MP2/aug-cc-pVTZ level. We found that the electron-withdrawing halogen substituents on the vicinal carbon cause the fluorine atom, participating in the hydrogen bond for...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9090643/ https://www.ncbi.nlm.nih.gov/pubmed/35558337 http://dx.doi.org/10.1039/c8ra08122k |