Cargando…
Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect
An intensification of the “electrophile–nucleophile” synergistic effect was achieved in a microreactor for the coupling reaction of CO(2) and epoxides mediated by the binary Al complex/ternary ammonium salt catalyst system. The microreactor technology is proven to be a powerful tool for the preparat...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2018
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9090913/ https://www.ncbi.nlm.nih.gov/pubmed/35558338 http://dx.doi.org/10.1039/c8ra07236a |
_version_ | 1784704826874003456 |
---|---|
author | Li, Ming-Ran Zhang, Ming-Chao Yue, Tian-Jun Lu, Xiao-Bing Ren, Wei-Min |
author_facet | Li, Ming-Ran Zhang, Ming-Chao Yue, Tian-Jun Lu, Xiao-Bing Ren, Wei-Min |
author_sort | Li, Ming-Ran |
collection | PubMed |
description | An intensification of the “electrophile–nucleophile” synergistic effect was achieved in a microreactor for the coupling reaction of CO(2) and epoxides mediated by the binary Al complex/ternary ammonium salt catalyst system. The microreactor technology is proven to be a powerful tool for the preparation of cyclic carbonates with an improved reaction rate and a wide substrate scope. |
format | Online Article Text |
id | pubmed-9090913 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90909132022-05-11 Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect Li, Ming-Ran Zhang, Ming-Chao Yue, Tian-Jun Lu, Xiao-Bing Ren, Wei-Min RSC Adv Chemistry An intensification of the “electrophile–nucleophile” synergistic effect was achieved in a microreactor for the coupling reaction of CO(2) and epoxides mediated by the binary Al complex/ternary ammonium salt catalyst system. The microreactor technology is proven to be a powerful tool for the preparation of cyclic carbonates with an improved reaction rate and a wide substrate scope. The Royal Society of Chemistry 2018-11-23 /pmc/articles/PMC9090913/ /pubmed/35558338 http://dx.doi.org/10.1039/c8ra07236a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Li, Ming-Ran Zhang, Ming-Chao Yue, Tian-Jun Lu, Xiao-Bing Ren, Wei-Min Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect |
title | Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect |
title_full | Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect |
title_fullStr | Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect |
title_full_unstemmed | Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect |
title_short | Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect |
title_sort | highly efficient conversion of co(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9090913/ https://www.ncbi.nlm.nih.gov/pubmed/35558338 http://dx.doi.org/10.1039/c8ra07236a |
work_keys_str_mv | AT limingran highlyefficientconversionofco2tocycliccarbonateswithabinarycatalystsysteminamicroreactorintensificationofelectrophilenucleophilesynergisticeffect AT zhangmingchao highlyefficientconversionofco2tocycliccarbonateswithabinarycatalystsysteminamicroreactorintensificationofelectrophilenucleophilesynergisticeffect AT yuetianjun highlyefficientconversionofco2tocycliccarbonateswithabinarycatalystsysteminamicroreactorintensificationofelectrophilenucleophilesynergisticeffect AT luxiaobing highlyefficientconversionofco2tocycliccarbonateswithabinarycatalystsysteminamicroreactorintensificationofelectrophilenucleophilesynergisticeffect AT renweimin highlyefficientconversionofco2tocycliccarbonateswithabinarycatalystsysteminamicroreactorintensificationofelectrophilenucleophilesynergisticeffect |