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Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect

An intensification of the “electrophile–nucleophile” synergistic effect was achieved in a microreactor for the coupling reaction of CO(2) and epoxides mediated by the binary Al complex/ternary ammonium salt catalyst system. The microreactor technology is proven to be a powerful tool for the preparat...

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Autores principales: Li, Ming-Ran, Zhang, Ming-Chao, Yue, Tian-Jun, Lu, Xiao-Bing, Ren, Wei-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9090913/
https://www.ncbi.nlm.nih.gov/pubmed/35558338
http://dx.doi.org/10.1039/c8ra07236a
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author Li, Ming-Ran
Zhang, Ming-Chao
Yue, Tian-Jun
Lu, Xiao-Bing
Ren, Wei-Min
author_facet Li, Ming-Ran
Zhang, Ming-Chao
Yue, Tian-Jun
Lu, Xiao-Bing
Ren, Wei-Min
author_sort Li, Ming-Ran
collection PubMed
description An intensification of the “electrophile–nucleophile” synergistic effect was achieved in a microreactor for the coupling reaction of CO(2) and epoxides mediated by the binary Al complex/ternary ammonium salt catalyst system. The microreactor technology is proven to be a powerful tool for the preparation of cyclic carbonates with an improved reaction rate and a wide substrate scope.
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spelling pubmed-90909132022-05-11 Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect Li, Ming-Ran Zhang, Ming-Chao Yue, Tian-Jun Lu, Xiao-Bing Ren, Wei-Min RSC Adv Chemistry An intensification of the “electrophile–nucleophile” synergistic effect was achieved in a microreactor for the coupling reaction of CO(2) and epoxides mediated by the binary Al complex/ternary ammonium salt catalyst system. The microreactor technology is proven to be a powerful tool for the preparation of cyclic carbonates with an improved reaction rate and a wide substrate scope. The Royal Society of Chemistry 2018-11-23 /pmc/articles/PMC9090913/ /pubmed/35558338 http://dx.doi.org/10.1039/c8ra07236a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Li, Ming-Ran
Zhang, Ming-Chao
Yue, Tian-Jun
Lu, Xiao-Bing
Ren, Wei-Min
Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect
title Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect
title_full Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect
title_fullStr Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect
title_full_unstemmed Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect
title_short Highly efficient conversion of CO(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect
title_sort highly efficient conversion of co(2) to cyclic carbonates with a binary catalyst system in a microreactor: intensification of “electrophile–nucleophile” synergistic effect
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9090913/
https://www.ncbi.nlm.nih.gov/pubmed/35558338
http://dx.doi.org/10.1039/c8ra07236a
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