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Pb(II)-catalyzed transformation of aromatic nitriles to heptanitrogen anions via sodium azide: a combined experimental and theoretical study
Under hydrothermal conditions, an open-chain N(7)(3−) anion stabilized in a metal–organic framework (MOF) was achieved for the first time via the in situ reaction of 4-fluorobenzonitrile and sodium azide with Pb(2+) ion as catalyst. The anion with C(2h) symmetry in the MOF was studied by FT-IR, sing...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9091291/ https://www.ncbi.nlm.nih.gov/pubmed/35558235 http://dx.doi.org/10.1039/c8ra08486f |