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Na–Ga–Si type-I clathrate single crystals grown via Na evaporation using Na–Ga and Na–Ga–Sn fluxes

Single crystals of a Na–Ga–Si clathrate, Na(8)Ga(5.70)Si(40.30), of size 2.9 mm were grown via the evaporation of Na from a Na–Ga–Si melt with the molar ratio of Na : Ga : Si = 4 : 1 : 2 at 773 K for 21 h under an Ar atmosphere. The crystal structure was analyzed using X-ray diffraction with the mod...

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Detalles Bibliográficos
Autores principales: Urushiyama, Hironao, Morito, Haruhiko, Yamane, Hisanori, Terauchi, Masami
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9091382/
https://www.ncbi.nlm.nih.gov/pubmed/35557917
http://dx.doi.org/10.1039/c8ra07971d