Insights into Ag(i)-catalyzed addition reactions of amino alcohols to electron-deficient olefins: competing mechanisms, role of catalyst, and origin of chemoselectivity

The competing mechanisms of Ag(i)-catalyzed chemoselective addition reactions of amino alcohols and electron-deficient olefins leading to the O-adduct or N-adduct products were systematically studied with density functional theory methods. Calculations indicate that the AgHMDS/dppe versus AgOAc/dppe...

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Detalles Bibliográficos
Autores principales: Liu, Chunhui, Han, Peilin, Xie, Zhizhong, Xu, Zhihong, Wei, Donghui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9091461/
https://www.ncbi.nlm.nih.gov/pubmed/35558202
http://dx.doi.org/10.1039/c8ra09065c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9091461/
https://www.ncbi.nlm.nih.gov/pubmed/35558202
http://dx.doi.org/10.1039/c8ra09065c

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