A straightforward and convenient synthesis of functionalized allyl thiosulfonates and allyl disulfanes

A practical, highly flexible and eco-friendly method has been developed for the synthesis of allyl thiosulfonates using Morita–Baylis–Hillman (MBH) allyl bromides and sodium arylthiosulfonates, which were readily assembled without any reagent/catalyst. Moreover, the allyl thiosulfonates were success...

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Detalles Bibliográficos
Autores principales: Reddy, Raju Jannapu, Waheed, Md., Kumar, Jangam Jagadesh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9091482/
https://www.ncbi.nlm.nih.gov/pubmed/35558195
http://dx.doi.org/10.1039/c8ra06938g
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author Reddy, Raju Jannapu
Waheed, Md.
Kumar, Jangam Jagadesh
author_facet Reddy, Raju Jannapu
Waheed, Md.
Kumar, Jangam Jagadesh
author_sort Reddy, Raju Jannapu
collection PubMed
description A practical, highly flexible and eco-friendly method has been developed for the synthesis of allyl thiosulfonates using Morita–Baylis–Hillman (MBH) allyl bromides and sodium arylthiosulfonates, which were readily assembled without any reagent/catalyst. Moreover, the allyl thiosulfonates were successfully transformed into a set of two synthetically viable diallyl disulfanes and unsymmetrical allyl disulfanes in the presence of Cs(2)CO(3). The present protocols are operationally simple and convenient to generate a wide range of functionalized allyl thiosulfonates and allyl disulfanes in good to excellent yields.
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spelling pubmed-90914822022-05-11 A straightforward and convenient synthesis of functionalized allyl thiosulfonates and allyl disulfanes Reddy, Raju Jannapu Waheed, Md. Kumar, Jangam Jagadesh RSC Adv Chemistry A practical, highly flexible and eco-friendly method has been developed for the synthesis of allyl thiosulfonates using Morita–Baylis–Hillman (MBH) allyl bromides and sodium arylthiosulfonates, which were readily assembled without any reagent/catalyst. Moreover, the allyl thiosulfonates were successfully transformed into a set of two synthetically viable diallyl disulfanes and unsymmetrical allyl disulfanes in the presence of Cs(2)CO(3). The present protocols are operationally simple and convenient to generate a wide range of functionalized allyl thiosulfonates and allyl disulfanes in good to excellent yields. The Royal Society of Chemistry 2018-12-04 /pmc/articles/PMC9091482/ /pubmed/35558195 http://dx.doi.org/10.1039/c8ra06938g Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Reddy, Raju Jannapu
Waheed, Md.
Kumar, Jangam Jagadesh
A straightforward and convenient synthesis of functionalized allyl thiosulfonates and allyl disulfanes
title A straightforward and convenient synthesis of functionalized allyl thiosulfonates and allyl disulfanes
title_full A straightforward and convenient synthesis of functionalized allyl thiosulfonates and allyl disulfanes
title_fullStr A straightforward and convenient synthesis of functionalized allyl thiosulfonates and allyl disulfanes
title_full_unstemmed A straightforward and convenient synthesis of functionalized allyl thiosulfonates and allyl disulfanes
title_short A straightforward and convenient synthesis of functionalized allyl thiosulfonates and allyl disulfanes
title_sort straightforward and convenient synthesis of functionalized allyl thiosulfonates and allyl disulfanes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9091482/
https://www.ncbi.nlm.nih.gov/pubmed/35558195
http://dx.doi.org/10.1039/c8ra06938g
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