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Adsorption behavior and mechanism of β-cyclodextrin–styrene-based polymer for cationic dyes

Cyclodextrin polymers are efficient adsorbents for dye adsorption. Herein, a β-cyclodextrin polymer (β-CDSP) with carboxyl groups and benzene rings was prepared via free radical polymerization of β-cyclodextrin-maleate and styrene. The adsorption performance of β-CDSP was studied by adsorbing neutra...

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Detalles Bibliográficos
Autores principales: Li, Xia, Xie, Long, Yang, Xuan, Nie, Xiaojuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9091483/
https://www.ncbi.nlm.nih.gov/pubmed/35558233
http://dx.doi.org/10.1039/c8ra07709f
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author Li, Xia
Xie, Long
Yang, Xuan
Nie, Xiaojuan
author_facet Li, Xia
Xie, Long
Yang, Xuan
Nie, Xiaojuan
author_sort Li, Xia
collection PubMed
description Cyclodextrin polymers are efficient adsorbents for dye adsorption. Herein, a β-cyclodextrin polymer (β-CDSP) with carboxyl groups and benzene rings was prepared via free radical polymerization of β-cyclodextrin-maleate and styrene. The adsorption performance of β-CDSP was studied by adsorbing neutral red (NR), basic fuchsin (BF) and safranine T (ST) dyes under different adsorption conditions (e.g., adsorption time, temperature and pH of the solution). The results showed that the adsorption of BF and ST was faster and better than that of NR. The adsorption kinetic behavior fitted well with both the pseudo-first-order and the pseudo-second-order models for NR and BF, but it fitted better with the latter for ST. The adsorption equilibrium data followed the Langmuir isotherm model. The adsorption process was endothermic and spontaneous, and a higher temperature was favorable for dye adsorption. Higher q(t) values were obtained in a basic medium, which resulted from the electrostatic interactions between β-CDSP and cationic dyes. Furthermore, inclusion complexion and π–π interactions also contributed to the dye adsorption. The stability and reusability of β-CDSP were estimated by four regeneration cycles.
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spelling pubmed-90914832022-05-11 Adsorption behavior and mechanism of β-cyclodextrin–styrene-based polymer for cationic dyes Li, Xia Xie, Long Yang, Xuan Nie, Xiaojuan RSC Adv Chemistry Cyclodextrin polymers are efficient adsorbents for dye adsorption. Herein, a β-cyclodextrin polymer (β-CDSP) with carboxyl groups and benzene rings was prepared via free radical polymerization of β-cyclodextrin-maleate and styrene. The adsorption performance of β-CDSP was studied by adsorbing neutral red (NR), basic fuchsin (BF) and safranine T (ST) dyes under different adsorption conditions (e.g., adsorption time, temperature and pH of the solution). The results showed that the adsorption of BF and ST was faster and better than that of NR. The adsorption kinetic behavior fitted well with both the pseudo-first-order and the pseudo-second-order models for NR and BF, but it fitted better with the latter for ST. The adsorption equilibrium data followed the Langmuir isotherm model. The adsorption process was endothermic and spontaneous, and a higher temperature was favorable for dye adsorption. Higher q(t) values were obtained in a basic medium, which resulted from the electrostatic interactions between β-CDSP and cationic dyes. Furthermore, inclusion complexion and π–π interactions also contributed to the dye adsorption. The stability and reusability of β-CDSP were estimated by four regeneration cycles. The Royal Society of Chemistry 2018-12-04 /pmc/articles/PMC9091483/ /pubmed/35558233 http://dx.doi.org/10.1039/c8ra07709f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Li, Xia
Xie, Long
Yang, Xuan
Nie, Xiaojuan
Adsorption behavior and mechanism of β-cyclodextrin–styrene-based polymer for cationic dyes
title Adsorption behavior and mechanism of β-cyclodextrin–styrene-based polymer for cationic dyes
title_full Adsorption behavior and mechanism of β-cyclodextrin–styrene-based polymer for cationic dyes
title_fullStr Adsorption behavior and mechanism of β-cyclodextrin–styrene-based polymer for cationic dyes
title_full_unstemmed Adsorption behavior and mechanism of β-cyclodextrin–styrene-based polymer for cationic dyes
title_short Adsorption behavior and mechanism of β-cyclodextrin–styrene-based polymer for cationic dyes
title_sort adsorption behavior and mechanism of β-cyclodextrin–styrene-based polymer for cationic dyes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9091483/
https://www.ncbi.nlm.nih.gov/pubmed/35558233
http://dx.doi.org/10.1039/c8ra07709f
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