Synthesis of mixed musks via Eschenmoser–Tanabe fragmentation, enyne metathesis and Diels–Alder reaction as key steps

Musk analogues containing different macrocyclic ring systems as well as different annulated ring systems were synthesised by a simple and useful strategy. This strategy includes Eschenmoser–Tanabe fragmentation, enyne metathesis and Diels–Alder reaction as key steps. Starting from easily available (...

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Detalles Bibliográficos
Autores principales: Kotha, Sambasivarao, Agrawal, Arpit, Tangella, Yellaiah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9092383/
https://www.ncbi.nlm.nih.gov/pubmed/35558836
http://dx.doi.org/10.1039/d2ra01458k
Descripción
Sumario:Musk analogues containing different macrocyclic ring systems as well as different annulated ring systems were synthesised by a simple and useful strategy. This strategy includes Eschenmoser–Tanabe fragmentation, enyne metathesis and Diels–Alder reaction as key steps. Starting from easily available (n) macrocyclic ketones, (n + 3) macrocyclic systems were assembled using the basic organic reactions.

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