Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds

Electrochemical and theoretical investigations over triple-quadruple-, quintuple-, and sextuple-decker sandwich-type compounds {[(Pc*)Sm][(Pc*)Cd(n)(Pc*)(n)][Sm(Pc*)]} (n = 0–3) elucidate successive π–π interaction-linked extension in the perpendicular direction of the phthalocyanine plane along wit...

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Detalles Bibliográficos
Autores principales: Chen, Xin, Qi, Dongdong, Liu, Chao, Wang, Hailong, Xie, Zheng, Chen, Tse-Wei, Chen, Shen-Ming, Tseng, Tien-Wen, Jiang, Jianzhuang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9092954/
https://www.ncbi.nlm.nih.gov/pubmed/35558861
http://dx.doi.org/10.1039/c9ra07847a
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author Chen, Xin
Qi, Dongdong
Liu, Chao
Wang, Hailong
Xie, Zheng
Chen, Tse-Wei
Chen, Shen-Ming
Tseng, Tien-Wen
Jiang, Jianzhuang
author_facet Chen, Xin
Qi, Dongdong
Liu, Chao
Wang, Hailong
Xie, Zheng
Chen, Tse-Wei
Chen, Shen-Ming
Tseng, Tien-Wen
Jiang, Jianzhuang
author_sort Chen, Xin
collection PubMed
description Electrochemical and theoretical investigations over triple-quadruple-, quintuple-, and sextuple-decker sandwich-type compounds {[(Pc*)Sm][(Pc*)Cd(n)(Pc*)(n)][Sm(Pc*)]} (n = 0–3) elucidate successive π–π interaction-linked extension in the perpendicular direction of the phthalocyanine plane along with increasing the stacked tetrapyrrole number, significantly improving the nonlinear optical properties including effective imaginary third order molecular hyperpolarizability and optical limiting threshold.
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spelling pubmed-90929542022-05-11 Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds Chen, Xin Qi, Dongdong Liu, Chao Wang, Hailong Xie, Zheng Chen, Tse-Wei Chen, Shen-Ming Tseng, Tien-Wen Jiang, Jianzhuang RSC Adv Chemistry Electrochemical and theoretical investigations over triple-quadruple-, quintuple-, and sextuple-decker sandwich-type compounds {[(Pc*)Sm][(Pc*)Cd(n)(Pc*)(n)][Sm(Pc*)]} (n = 0–3) elucidate successive π–π interaction-linked extension in the perpendicular direction of the phthalocyanine plane along with increasing the stacked tetrapyrrole number, significantly improving the nonlinear optical properties including effective imaginary third order molecular hyperpolarizability and optical limiting threshold. The Royal Society of Chemistry 2020-01-02 /pmc/articles/PMC9092954/ /pubmed/35558861 http://dx.doi.org/10.1039/c9ra07847a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Chen, Xin
Qi, Dongdong
Liu, Chao
Wang, Hailong
Xie, Zheng
Chen, Tse-Wei
Chen, Shen-Ming
Tseng, Tien-Wen
Jiang, Jianzhuang
Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds
title Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds
title_full Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds
title_fullStr Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds
title_full_unstemmed Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds
title_short Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds
title_sort elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9092954/
https://www.ncbi.nlm.nih.gov/pubmed/35558861
http://dx.doi.org/10.1039/c9ra07847a
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