Assessment of TiO(2) Blocking Layers for Cu(II/I)-Electrolyte Dye-Sensitized Solar Cells by Electrochemical Impedance Spectroscopy

[Image: see text] The TiO(2) blocking layer in dye-sensitized solar cells is the most difficult component to evaluate at thicknesses below 50 nm, but it is crucial for the power conversion efficiency. Here, the electrode capacitance of TiO(2) blocking layers is tested in aqueous [Fe(CN)(6)](3–/4–) and correlated to the performance of photoanodes in devices based on a [Cu(tmby)(2)](2+/+) electrolyte. The effects of the blocking layer on electronic recombination in the devices are illustrated with transient photovoltage methods and electrochemical impedance analysis. We have thus demonstrated a feasible and facile method to assess TiO(2) blocking layers for the fabrication of dye-sensitized solar cells.