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Synthesis and Characterization of Alkyne-Functionalized Photo-Cross-Linkable Polyesters

[Image: see text] An alkyne-functionalized elastomer derived from sebacic acid, 1,3-propanediol, and alkyne-functionalized serinol is synthesized via melt condensation. A low-power UV lamp triggers the cross-linking rapidly via thiol–yne click chemistry. The cross-linking behavior is studied by phot...

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Autores principales: Ma, Warrick, Ding, Xiaochu, Chen, Ying, Wang, Yadong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9096926/
https://www.ncbi.nlm.nih.gov/pubmed/35571817
http://dx.doi.org/10.1021/acsomega.2c00272
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author Ma, Warrick
Ding, Xiaochu
Chen, Ying
Wang, Yadong
author_facet Ma, Warrick
Ding, Xiaochu
Chen, Ying
Wang, Yadong
author_sort Ma, Warrick
collection PubMed
description [Image: see text] An alkyne-functionalized elastomer derived from sebacic acid, 1,3-propanediol, and alkyne-functionalized serinol is synthesized via melt condensation. A low-power UV lamp triggers the cross-linking rapidly via thiol–yne click chemistry. The cross-linking behavior is studied by photorheology and NMR spectroscopy. The resultant elastomer possesses mechanical properties similar to those of human soft tissues and exhibits in vitro degradability and good cytocompatibility.
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spelling pubmed-90969262022-05-13 Synthesis and Characterization of Alkyne-Functionalized Photo-Cross-Linkable Polyesters Ma, Warrick Ding, Xiaochu Chen, Ying Wang, Yadong ACS Omega [Image: see text] An alkyne-functionalized elastomer derived from sebacic acid, 1,3-propanediol, and alkyne-functionalized serinol is synthesized via melt condensation. A low-power UV lamp triggers the cross-linking rapidly via thiol–yne click chemistry. The cross-linking behavior is studied by photorheology and NMR spectroscopy. The resultant elastomer possesses mechanical properties similar to those of human soft tissues and exhibits in vitro degradability and good cytocompatibility. American Chemical Society 2022-04-26 /pmc/articles/PMC9096926/ /pubmed/35571817 http://dx.doi.org/10.1021/acsomega.2c00272 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Ma, Warrick
Ding, Xiaochu
Chen, Ying
Wang, Yadong
Synthesis and Characterization of Alkyne-Functionalized Photo-Cross-Linkable Polyesters
title Synthesis and Characterization of Alkyne-Functionalized Photo-Cross-Linkable Polyesters
title_full Synthesis and Characterization of Alkyne-Functionalized Photo-Cross-Linkable Polyesters
title_fullStr Synthesis and Characterization of Alkyne-Functionalized Photo-Cross-Linkable Polyesters
title_full_unstemmed Synthesis and Characterization of Alkyne-Functionalized Photo-Cross-Linkable Polyesters
title_short Synthesis and Characterization of Alkyne-Functionalized Photo-Cross-Linkable Polyesters
title_sort synthesis and characterization of alkyne-functionalized photo-cross-linkable polyesters
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9096926/
https://www.ncbi.nlm.nih.gov/pubmed/35571817
http://dx.doi.org/10.1021/acsomega.2c00272
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