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Hybrid Surface-Enhanced Raman Scattering Substrates for the Trace Detection of Ammonium Nitrate, Thiram, and Nile Blue
[Image: see text] We report the fabrication and performance evaluation of hybrid surface-enhanced Raman scattering (SERS) substrates involving laser ablation and chemical routes for the trace-level detection of various analyte molecules. Initially, picosecond laser ablation experiments under ambient...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9096967/ https://www.ncbi.nlm.nih.gov/pubmed/35571848 http://dx.doi.org/10.1021/acsomega.2c01095 |
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author | Rathod, Jagannath Byram, Chandu Kanaka, Ravi Kumar Sree Satya Bharati, Moram Banerjee, Dipanjan Akkanaboina, Mangababu Soma, Venugopal Rao |
author_facet | Rathod, Jagannath Byram, Chandu Kanaka, Ravi Kumar Sree Satya Bharati, Moram Banerjee, Dipanjan Akkanaboina, Mangababu Soma, Venugopal Rao |
author_sort | Rathod, Jagannath |
collection | PubMed |
description | [Image: see text] We report the fabrication and performance evaluation of hybrid surface-enhanced Raman scattering (SERS) substrates involving laser ablation and chemical routes for the trace-level detection of various analyte molecules. Initially, picosecond laser ablation experiments under ambient conditions were performed on pure silver (Ag) and gold (Au) substrates to achieve distinct nanosized features on the surface. The properties of the generated surface features on laser-processed portions of Ag/Au targets were systematically analyzed using UV–visible reflection and field emission scanning electron microscopy studies. Later, hybrid-SERS substrates were achieved by grafting the chemically synthesized Au nanostars on the plain and laser-processed plasmonic targets. Subsequently, we employed these as SERS platforms for the detection of a pesticide (thiram), a molecule used in explosive compositions [ammonium nitrate (AN)], and a dye molecule [Nile blue (NB)]. A comparative SERS study between the Au nanostar-decorated bare glass, silicon, Ag, Au, and laser-processed Ag and Au targets has been established. Our studies and the obtained data have unambiguously determined that laser-processed Ag structures have demonstrated reasonably good enhancements in the Raman signal intensities for distinct analytes among other substrates. Importantly, the fabricated hybrid SERS substrate of “Au nanostar-decorated laser-processed Ag” exhibited up to eight times enhancement in the SERS intensity compared to laser-processed Ag (without nanostars), as well as up to three times enhancement than the Au nanostar-loaded plain Ag substrates. Additionally, the achieved detection limits from the Au nanostar-decorated laser-processed Ag SERS substrate were ∼50 pM, ∼5 nM, and ∼5 μM for NB, thiram, and AN, respectively. The estimated enhancement factors accomplished from the Au nanostar-decorated laser-processed Ag substrate were ∼10(6), ∼10(6), and ∼10(4) for NB, thiram, and AN, respectively. |
format | Online Article Text |
id | pubmed-9096967 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-90969672022-05-13 Hybrid Surface-Enhanced Raman Scattering Substrates for the Trace Detection of Ammonium Nitrate, Thiram, and Nile Blue Rathod, Jagannath Byram, Chandu Kanaka, Ravi Kumar Sree Satya Bharati, Moram Banerjee, Dipanjan Akkanaboina, Mangababu Soma, Venugopal Rao ACS Omega [Image: see text] We report the fabrication and performance evaluation of hybrid surface-enhanced Raman scattering (SERS) substrates involving laser ablation and chemical routes for the trace-level detection of various analyte molecules. Initially, picosecond laser ablation experiments under ambient conditions were performed on pure silver (Ag) and gold (Au) substrates to achieve distinct nanosized features on the surface. The properties of the generated surface features on laser-processed portions of Ag/Au targets were systematically analyzed using UV–visible reflection and field emission scanning electron microscopy studies. Later, hybrid-SERS substrates were achieved by grafting the chemically synthesized Au nanostars on the plain and laser-processed plasmonic targets. Subsequently, we employed these as SERS platforms for the detection of a pesticide (thiram), a molecule used in explosive compositions [ammonium nitrate (AN)], and a dye molecule [Nile blue (NB)]. A comparative SERS study between the Au nanostar-decorated bare glass, silicon, Ag, Au, and laser-processed Ag and Au targets has been established. Our studies and the obtained data have unambiguously determined that laser-processed Ag structures have demonstrated reasonably good enhancements in the Raman signal intensities for distinct analytes among other substrates. Importantly, the fabricated hybrid SERS substrate of “Au nanostar-decorated laser-processed Ag” exhibited up to eight times enhancement in the SERS intensity compared to laser-processed Ag (without nanostars), as well as up to three times enhancement than the Au nanostar-loaded plain Ag substrates. Additionally, the achieved detection limits from the Au nanostar-decorated laser-processed Ag SERS substrate were ∼50 pM, ∼5 nM, and ∼5 μM for NB, thiram, and AN, respectively. The estimated enhancement factors accomplished from the Au nanostar-decorated laser-processed Ag substrate were ∼10(6), ∼10(6), and ∼10(4) for NB, thiram, and AN, respectively. American Chemical Society 2022-04-28 /pmc/articles/PMC9096967/ /pubmed/35571848 http://dx.doi.org/10.1021/acsomega.2c01095 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Rathod, Jagannath Byram, Chandu Kanaka, Ravi Kumar Sree Satya Bharati, Moram Banerjee, Dipanjan Akkanaboina, Mangababu Soma, Venugopal Rao Hybrid Surface-Enhanced Raman Scattering Substrates for the Trace Detection of Ammonium Nitrate, Thiram, and Nile Blue |
title | Hybrid Surface-Enhanced Raman Scattering Substrates
for the Trace Detection of Ammonium Nitrate, Thiram, and Nile Blue |
title_full | Hybrid Surface-Enhanced Raman Scattering Substrates
for the Trace Detection of Ammonium Nitrate, Thiram, and Nile Blue |
title_fullStr | Hybrid Surface-Enhanced Raman Scattering Substrates
for the Trace Detection of Ammonium Nitrate, Thiram, and Nile Blue |
title_full_unstemmed | Hybrid Surface-Enhanced Raman Scattering Substrates
for the Trace Detection of Ammonium Nitrate, Thiram, and Nile Blue |
title_short | Hybrid Surface-Enhanced Raman Scattering Substrates
for the Trace Detection of Ammonium Nitrate, Thiram, and Nile Blue |
title_sort | hybrid surface-enhanced raman scattering substrates
for the trace detection of ammonium nitrate, thiram, and nile blue |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9096967/ https://www.ncbi.nlm.nih.gov/pubmed/35571848 http://dx.doi.org/10.1021/acsomega.2c01095 |
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