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Temperature-Induced Structure Transformation from Co(0.85)Se to Orthorhombic Phase CoSe(2) Realizing Enhanced Hydrogen Evolution Catalysis

[Image: see text] Transition-metal chalcogenides (TMC) have been widely studied as active electrocatalysts toward the hydrogen evolution reaction due to their suitable d-electron configuration and relatively high electrical conductivity. Herein, we develop a feasible method to synthesize an orthorho...

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Detalles Bibliográficos
Autores principales: Bai, Jing, Wang, Yechen, Wang, Yange, Zhang, Tiantian, Dong, Gang, Geng, Dongsheng, Zhao, Dongjie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9097193/
https://www.ncbi.nlm.nih.gov/pubmed/35571852
http://dx.doi.org/10.1021/acsomega.2c01020
Descripción
Sumario:[Image: see text] Transition-metal chalcogenides (TMC) have been widely studied as active electrocatalysts toward the hydrogen evolution reaction due to their suitable d-electron configuration and relatively high electrical conductivity. Herein, we develop a feasible method to synthesize an orthorhombic phase of CoSe(2) (o-CoSe(2)) from the regeneration of Co(0.85)Se, where the temperature plays a key role in controlling the structure transformation. To the best of our knowledge, this is the first report about this synthetic route for o-CoSe(2). The resulting o-CoSe(2) catalysts exhibit enhanced hydrogen evolution reaction performance with an overpotential of 220 mV to reach 10 mA cm(–2) in 1.0 M KOH. Density functional theory calculations further reveal that the change in the Gibbs free energy of hydrogen, water adsorption energy, and the downshifted d-band center make o-CoSe(2) more suitable for accelerating the HER process.