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Temperature-Induced Structure Transformation from Co(0.85)Se to Orthorhombic Phase CoSe(2) Realizing Enhanced Hydrogen Evolution Catalysis
[Image: see text] Transition-metal chalcogenides (TMC) have been widely studied as active electrocatalysts toward the hydrogen evolution reaction due to their suitable d-electron configuration and relatively high electrical conductivity. Herein, we develop a feasible method to synthesize an orthorho...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9097193/ https://www.ncbi.nlm.nih.gov/pubmed/35571852 http://dx.doi.org/10.1021/acsomega.2c01020 |
Sumario: | [Image: see text] Transition-metal chalcogenides (TMC) have been widely studied as active electrocatalysts toward the hydrogen evolution reaction due to their suitable d-electron configuration and relatively high electrical conductivity. Herein, we develop a feasible method to synthesize an orthorhombic phase of CoSe(2) (o-CoSe(2)) from the regeneration of Co(0.85)Se, where the temperature plays a key role in controlling the structure transformation. To the best of our knowledge, this is the first report about this synthetic route for o-CoSe(2). The resulting o-CoSe(2) catalysts exhibit enhanced hydrogen evolution reaction performance with an overpotential of 220 mV to reach 10 mA cm(–2) in 1.0 M KOH. Density functional theory calculations further reveal that the change in the Gibbs free energy of hydrogen, water adsorption energy, and the downshifted d-band center make o-CoSe(2) more suitable for accelerating the HER process. |
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