Solvent Drives Switching between Λ and Δ Metal Center Stereochemistry of M(8)L(6) Cubic Cages

[Image: see text] An enantiopure ligand with four bidentate metal-binding sites and four (S)-carbon stereocenters self-assembles with octahedral Zn(II) or Co(II) to produce O-symmetric M(8)L(6) coordination cages. The Λ- or Δ-handedness of the metal centers forming the corners of these cages is dete...

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Detalles Bibliográficos
Autores principales: Xue, Weichao, Ronson, Tanya K., Lu, Zifei, Nitschke, Jonathan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9098163/
https://www.ncbi.nlm.nih.gov/pubmed/35364808
http://dx.doi.org/10.1021/jacs.2c00245

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9098163/
https://www.ncbi.nlm.nih.gov/pubmed/35364808
http://dx.doi.org/10.1021/jacs.2c00245

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