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Solvent Drives Switching between Λ and Δ Metal Center Stereochemistry of M(8)L(6) Cubic Cages
[Image: see text] An enantiopure ligand with four bidentate metal-binding sites and four (S)-carbon stereocenters self-assembles with octahedral Zn(II) or Co(II) to produce O-symmetric M(8)L(6) coordination cages. The Λ- or Δ-handedness of the metal centers forming the corners of these cages is dete...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9098163/ https://www.ncbi.nlm.nih.gov/pubmed/35364808 http://dx.doi.org/10.1021/jacs.2c00245 |