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Catalytic and Stoichiometric Baeyer–Villiger Oxidation Mediated by Nonheme Peroxo-Diiron(III), Acylperoxo, and Iodosylbenzene Iron(III) Intermediates
In this paper we describe a detailed mechanistic studies on the [Fe(II)(PBO)(2)(CF(3)SO(3))(2)] (1), [Fe(II)(PBT)(2)(CF(3)SO(3))(2)] (2), and [Fe(II)(PBI)(3)](CF(3)SO(3))(2) (3)-catalyzed (PBO = 2-(2′-pyridyl)benzoxazole, PBT = 2-(2′-pyridyl)benzthiazole, PBI = 2-(2′-pyridyl)benzimidazole) Baeyer–Vi...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9100052/ https://www.ncbi.nlm.nih.gov/pubmed/35566165 http://dx.doi.org/10.3390/molecules27092814 |