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Development of a Highly Efficient Environmentally Friendly Plasticizer
The purpose of this work is the synthesis of adipic acid ester and the study of the possibility of its use as a PVC plasticizer. The resulting butyl phenoxyethyl adipate was characterized by Fourier-transform infrared spectrometry, thermogravimetric analysis (TGA) and differential scanning calorimet...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9100690/ https://www.ncbi.nlm.nih.gov/pubmed/35567061 http://dx.doi.org/10.3390/polym14091888 |
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author | Vikhareva, Irina N. Aminova, Guliya K. Mazitova, Aliya K. |
author_facet | Vikhareva, Irina N. Aminova, Guliya K. Mazitova, Aliya K. |
author_sort | Vikhareva, Irina N. |
collection | PubMed |
description | The purpose of this work is the synthesis of adipic acid ester and the study of the possibility of its use as a PVC plasticizer. The resulting butyl phenoxyethyl adipate was characterized by Fourier-transform infrared spectrometry, thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The compatibility, effectiveness and plasticizing effect of butyl phenoxyethyl adipate in comparison with dioctylphthalate (DOP) were determined. The new environmentally friendly plasticizer has good compatibility with PVC and high thermal stability. The effectiveness of the plasticizing action of adipate based on the glass-transition temperature was 132.2 °C in relation to pure PVC and 7.7 °C in comparison to compounds based on DOP. An increase in the fluidity of the melt of polyvinyl chloride (PVC) compounds in the temperature range of 160–205 °C by 19–50% confirms a decrease in the energy intensity of the processes of manufacturing and the processing of polymer materials containing a new additive. |
format | Online Article Text |
id | pubmed-9100690 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-91006902022-05-14 Development of a Highly Efficient Environmentally Friendly Plasticizer Vikhareva, Irina N. Aminova, Guliya K. Mazitova, Aliya K. Polymers (Basel) Article The purpose of this work is the synthesis of adipic acid ester and the study of the possibility of its use as a PVC plasticizer. The resulting butyl phenoxyethyl adipate was characterized by Fourier-transform infrared spectrometry, thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The compatibility, effectiveness and plasticizing effect of butyl phenoxyethyl adipate in comparison with dioctylphthalate (DOP) were determined. The new environmentally friendly plasticizer has good compatibility with PVC and high thermal stability. The effectiveness of the plasticizing action of adipate based on the glass-transition temperature was 132.2 °C in relation to pure PVC and 7.7 °C in comparison to compounds based on DOP. An increase in the fluidity of the melt of polyvinyl chloride (PVC) compounds in the temperature range of 160–205 °C by 19–50% confirms a decrease in the energy intensity of the processes of manufacturing and the processing of polymer materials containing a new additive. MDPI 2022-05-05 /pmc/articles/PMC9100690/ /pubmed/35567061 http://dx.doi.org/10.3390/polym14091888 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Vikhareva, Irina N. Aminova, Guliya K. Mazitova, Aliya K. Development of a Highly Efficient Environmentally Friendly Plasticizer |
title | Development of a Highly Efficient Environmentally Friendly Plasticizer |
title_full | Development of a Highly Efficient Environmentally Friendly Plasticizer |
title_fullStr | Development of a Highly Efficient Environmentally Friendly Plasticizer |
title_full_unstemmed | Development of a Highly Efficient Environmentally Friendly Plasticizer |
title_short | Development of a Highly Efficient Environmentally Friendly Plasticizer |
title_sort | development of a highly efficient environmentally friendly plasticizer |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9100690/ https://www.ncbi.nlm.nih.gov/pubmed/35567061 http://dx.doi.org/10.3390/polym14091888 |
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