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Development of a Highly Efficient Environmentally Friendly Plasticizer

The purpose of this work is the synthesis of adipic acid ester and the study of the possibility of its use as a PVC plasticizer. The resulting butyl phenoxyethyl adipate was characterized by Fourier-transform infrared spectrometry, thermogravimetric analysis (TGA) and differential scanning calorimet...

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Autores principales: Vikhareva, Irina N., Aminova, Guliya K., Mazitova, Aliya K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9100690/
https://www.ncbi.nlm.nih.gov/pubmed/35567061
http://dx.doi.org/10.3390/polym14091888
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author Vikhareva, Irina N.
Aminova, Guliya K.
Mazitova, Aliya K.
author_facet Vikhareva, Irina N.
Aminova, Guliya K.
Mazitova, Aliya K.
author_sort Vikhareva, Irina N.
collection PubMed
description The purpose of this work is the synthesis of adipic acid ester and the study of the possibility of its use as a PVC plasticizer. The resulting butyl phenoxyethyl adipate was characterized by Fourier-transform infrared spectrometry, thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The compatibility, effectiveness and plasticizing effect of butyl phenoxyethyl adipate in comparison with dioctylphthalate (DOP) were determined. The new environmentally friendly plasticizer has good compatibility with PVC and high thermal stability. The effectiveness of the plasticizing action of adipate based on the glass-transition temperature was 132.2 °C in relation to pure PVC and 7.7 °C in comparison to compounds based on DOP. An increase in the fluidity of the melt of polyvinyl chloride (PVC) compounds in the temperature range of 160–205 °C by 19–50% confirms a decrease in the energy intensity of the processes of manufacturing and the processing of polymer materials containing a new additive.
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spelling pubmed-91006902022-05-14 Development of a Highly Efficient Environmentally Friendly Plasticizer Vikhareva, Irina N. Aminova, Guliya K. Mazitova, Aliya K. Polymers (Basel) Article The purpose of this work is the synthesis of adipic acid ester and the study of the possibility of its use as a PVC plasticizer. The resulting butyl phenoxyethyl adipate was characterized by Fourier-transform infrared spectrometry, thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The compatibility, effectiveness and plasticizing effect of butyl phenoxyethyl adipate in comparison with dioctylphthalate (DOP) were determined. The new environmentally friendly plasticizer has good compatibility with PVC and high thermal stability. The effectiveness of the plasticizing action of adipate based on the glass-transition temperature was 132.2 °C in relation to pure PVC and 7.7 °C in comparison to compounds based on DOP. An increase in the fluidity of the melt of polyvinyl chloride (PVC) compounds in the temperature range of 160–205 °C by 19–50% confirms a decrease in the energy intensity of the processes of manufacturing and the processing of polymer materials containing a new additive. MDPI 2022-05-05 /pmc/articles/PMC9100690/ /pubmed/35567061 http://dx.doi.org/10.3390/polym14091888 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Vikhareva, Irina N.
Aminova, Guliya K.
Mazitova, Aliya K.
Development of a Highly Efficient Environmentally Friendly Plasticizer
title Development of a Highly Efficient Environmentally Friendly Plasticizer
title_full Development of a Highly Efficient Environmentally Friendly Plasticizer
title_fullStr Development of a Highly Efficient Environmentally Friendly Plasticizer
title_full_unstemmed Development of a Highly Efficient Environmentally Friendly Plasticizer
title_short Development of a Highly Efficient Environmentally Friendly Plasticizer
title_sort development of a highly efficient environmentally friendly plasticizer
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9100690/
https://www.ncbi.nlm.nih.gov/pubmed/35567061
http://dx.doi.org/10.3390/polym14091888
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