Eco-Friendly, High-Ductility Slag/Fly-Ash-Based Engineered Cementitious Composite (ECC) Reinforced with PE Fibers

Engineered cementitious composites (ECCs) are a special class of ultra-ductile fiber-reinforced cementitious composites containing a significant amount of short discontinuous fibers. The distinctive tensile strain-hardening behavior of ECCs is the result of a systematic design based on the micromechanics of the fiber, matrix, and fiber–matrix interface. However, ECCs require extensive cement content, which is inconsistent with the goal of sustainable and green building materials. Consequently, the objective of this study is to investigate the mechanical performance of slag/fly-ash-based engineered cementitious composites (ECCs) reinforced with polyethylene (PE) fiber under axial compressive loading, as well as direct tensile and flexural strength tests. The composites’ microstructure and mineralogical composition were analyzed using images obtained from scanning electron microscopy (SEM), X-ray energy diffraction spectroscopy (EDS), X-ray powder diffraction (XRD), and X-ray fluorescence (XRF). The experimental results reveal that a slag-containing composite mixture shows strain-hardening behavior and comparable ductility properties to those of fly-ash-based composite mixtures. A ternary system of binder materials with 5% and 15% slag can increase the compressive strength of ECC by 3.5% and 34.9%, respectively, compared to slag-free ECC composite. Moreover, the microstructural results show that the slag-based cementitious matrix has a more closely cross-linked and dense microstructure at the matrix–aggregate interface. In addition, the concentration of particles on the surface of the fibers was higher in the slag-based cementitious composites than in the fly ash-based composite. This supports the concept that there is a stronger bonding between the fibers and matrix in the slag-based cementitious matrix than in fly-ash-based matrix.