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P–Ru-Complexes with a Chelate-Bridge-Switch: A Comparison of 2-Picolyl and 2-Pyridyloxy Moieties as Bridging Ligands

Starting from [Ru(pyO)(2)(nbd)] 1 and a N,P,N-tridentate ligand (2a: PhP(pic)(2), 2b: PhP(pyO)(2)) (nbd = 2,5-norbornadiene, pic = 2-picolyl = 2-pyridylmethyl, pyO = 2-pyridyloxy = pyridine-2-olate), the compounds [PhP(μ-pic)(2)(μ-pyO)Ru(κ(2)-pyO)] (3a) and [PhP(μ-pyO)(3)Ru(κ(2)-pyO)] (3b), respecti...

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Detalles Bibliográficos
Autores principales: Ehrlich, Lisa, Gericke, Robert, Brendler, Erica, Wagler, Jörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9103559/
https://www.ncbi.nlm.nih.gov/pubmed/35566128
http://dx.doi.org/10.3390/molecules27092778

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