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Physical Properties of Betaine-1,2-Propanediol-Based Deep Eutectic Solvents
Due to their splendid advantages, deep eutectic solvents have attracted high attention and are considered as analogues of ionic liquids. Deep eutectic solvents (DESs) are homogeneous mixtures formed by two or three green and cheap components through hydrogen bond, which is divided into hydrogen bond...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9104611/ https://www.ncbi.nlm.nih.gov/pubmed/35566953 http://dx.doi.org/10.3390/polym14091783 |
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author | Chen, Qicheng He, Nan Fan, Jing Song, Fenhong |
author_facet | Chen, Qicheng He, Nan Fan, Jing Song, Fenhong |
author_sort | Chen, Qicheng |
collection | PubMed |
description | Due to their splendid advantages, deep eutectic solvents have attracted high attention and are considered as analogues of ionic liquids. Deep eutectic solvents (DESs) are homogeneous mixtures formed by two or three green and cheap components through hydrogen bond, which is divided into hydrogen bond acceptors (HBA) and hydrogen bond donors (HBD). Recently, Betaine has been widely used as a hydrogen bond acceptor. In this work, four DESs were synthesized by blending betaine as HBA and 1,2-propanediol as HBD in four molar ratios (1:3.5, 1:4, 1:5, 1:6). Then, the physical properties of these DESs were measured. The density values were measured within the temperature range (293.15 K to 363.15 K) at atmospheric pressure, whereas the surface tension and viscosity data were determined in four and seven temperatures between 293.15 K and 353.15 K. The relationship between the density and surface tension with temperature have been analyzed and have been fitted as a linear function. The commonly used Arrhenius model was used to describe the dependence between viscosity and temperature. The results of this study are important not only for the DESs’ industrial applications but also for the research on their synthesis mechanism and microstructure. |
format | Online Article Text |
id | pubmed-9104611 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-91046112022-05-14 Physical Properties of Betaine-1,2-Propanediol-Based Deep Eutectic Solvents Chen, Qicheng He, Nan Fan, Jing Song, Fenhong Polymers (Basel) Article Due to their splendid advantages, deep eutectic solvents have attracted high attention and are considered as analogues of ionic liquids. Deep eutectic solvents (DESs) are homogeneous mixtures formed by two or three green and cheap components through hydrogen bond, which is divided into hydrogen bond acceptors (HBA) and hydrogen bond donors (HBD). Recently, Betaine has been widely used as a hydrogen bond acceptor. In this work, four DESs were synthesized by blending betaine as HBA and 1,2-propanediol as HBD in four molar ratios (1:3.5, 1:4, 1:5, 1:6). Then, the physical properties of these DESs were measured. The density values were measured within the temperature range (293.15 K to 363.15 K) at atmospheric pressure, whereas the surface tension and viscosity data were determined in four and seven temperatures between 293.15 K and 353.15 K. The relationship between the density and surface tension with temperature have been analyzed and have been fitted as a linear function. The commonly used Arrhenius model was used to describe the dependence between viscosity and temperature. The results of this study are important not only for the DESs’ industrial applications but also for the research on their synthesis mechanism and microstructure. MDPI 2022-04-27 /pmc/articles/PMC9104611/ /pubmed/35566953 http://dx.doi.org/10.3390/polym14091783 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Chen, Qicheng He, Nan Fan, Jing Song, Fenhong Physical Properties of Betaine-1,2-Propanediol-Based Deep Eutectic Solvents |
title | Physical Properties of Betaine-1,2-Propanediol-Based Deep Eutectic Solvents |
title_full | Physical Properties of Betaine-1,2-Propanediol-Based Deep Eutectic Solvents |
title_fullStr | Physical Properties of Betaine-1,2-Propanediol-Based Deep Eutectic Solvents |
title_full_unstemmed | Physical Properties of Betaine-1,2-Propanediol-Based Deep Eutectic Solvents |
title_short | Physical Properties of Betaine-1,2-Propanediol-Based Deep Eutectic Solvents |
title_sort | physical properties of betaine-1,2-propanediol-based deep eutectic solvents |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9104611/ https://www.ncbi.nlm.nih.gov/pubmed/35566953 http://dx.doi.org/10.3390/polym14091783 |
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