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Physical Properties of Betaine-1,2-Propanediol-Based Deep Eutectic Solvents

Due to their splendid advantages, deep eutectic solvents have attracted high attention and are considered as analogues of ionic liquids. Deep eutectic solvents (DESs) are homogeneous mixtures formed by two or three green and cheap components through hydrogen bond, which is divided into hydrogen bond...

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Autores principales: Chen, Qicheng, He, Nan, Fan, Jing, Song, Fenhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9104611/
https://www.ncbi.nlm.nih.gov/pubmed/35566953
http://dx.doi.org/10.3390/polym14091783
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author Chen, Qicheng
He, Nan
Fan, Jing
Song, Fenhong
author_facet Chen, Qicheng
He, Nan
Fan, Jing
Song, Fenhong
author_sort Chen, Qicheng
collection PubMed
description Due to their splendid advantages, deep eutectic solvents have attracted high attention and are considered as analogues of ionic liquids. Deep eutectic solvents (DESs) are homogeneous mixtures formed by two or three green and cheap components through hydrogen bond, which is divided into hydrogen bond acceptors (HBA) and hydrogen bond donors (HBD). Recently, Betaine has been widely used as a hydrogen bond acceptor. In this work, four DESs were synthesized by blending betaine as HBA and 1,2-propanediol as HBD in four molar ratios (1:3.5, 1:4, 1:5, 1:6). Then, the physical properties of these DESs were measured. The density values were measured within the temperature range (293.15 K to 363.15 K) at atmospheric pressure, whereas the surface tension and viscosity data were determined in four and seven temperatures between 293.15 K and 353.15 K. The relationship between the density and surface tension with temperature have been analyzed and have been fitted as a linear function. The commonly used Arrhenius model was used to describe the dependence between viscosity and temperature. The results of this study are important not only for the DESs’ industrial applications but also for the research on their synthesis mechanism and microstructure.
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spelling pubmed-91046112022-05-14 Physical Properties of Betaine-1,2-Propanediol-Based Deep Eutectic Solvents Chen, Qicheng He, Nan Fan, Jing Song, Fenhong Polymers (Basel) Article Due to their splendid advantages, deep eutectic solvents have attracted high attention and are considered as analogues of ionic liquids. Deep eutectic solvents (DESs) are homogeneous mixtures formed by two or three green and cheap components through hydrogen bond, which is divided into hydrogen bond acceptors (HBA) and hydrogen bond donors (HBD). Recently, Betaine has been widely used as a hydrogen bond acceptor. In this work, four DESs were synthesized by blending betaine as HBA and 1,2-propanediol as HBD in four molar ratios (1:3.5, 1:4, 1:5, 1:6). Then, the physical properties of these DESs were measured. The density values were measured within the temperature range (293.15 K to 363.15 K) at atmospheric pressure, whereas the surface tension and viscosity data were determined in four and seven temperatures between 293.15 K and 353.15 K. The relationship between the density and surface tension with temperature have been analyzed and have been fitted as a linear function. The commonly used Arrhenius model was used to describe the dependence between viscosity and temperature. The results of this study are important not only for the DESs’ industrial applications but also for the research on their synthesis mechanism and microstructure. MDPI 2022-04-27 /pmc/articles/PMC9104611/ /pubmed/35566953 http://dx.doi.org/10.3390/polym14091783 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Chen, Qicheng
He, Nan
Fan, Jing
Song, Fenhong
Physical Properties of Betaine-1,2-Propanediol-Based Deep Eutectic Solvents
title Physical Properties of Betaine-1,2-Propanediol-Based Deep Eutectic Solvents
title_full Physical Properties of Betaine-1,2-Propanediol-Based Deep Eutectic Solvents
title_fullStr Physical Properties of Betaine-1,2-Propanediol-Based Deep Eutectic Solvents
title_full_unstemmed Physical Properties of Betaine-1,2-Propanediol-Based Deep Eutectic Solvents
title_short Physical Properties of Betaine-1,2-Propanediol-Based Deep Eutectic Solvents
title_sort physical properties of betaine-1,2-propanediol-based deep eutectic solvents
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9104611/
https://www.ncbi.nlm.nih.gov/pubmed/35566953
http://dx.doi.org/10.3390/polym14091783
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