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Mitigation of Corrosion Initiated by Cl(−) and SO(4)(2−)-ions in Blast Furnace Cement Concrete Mixed with Sea Water

The use of blast furnace cement is an effective way to meet the requirements of sustainable development. However, CEM III/C is characterized by slow strength gain. The problem can be worse for plasticized reinforced blast furnace cement concretes mixed with sea water in view of shorter durability. T...

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Autores principales: Krivenko, Pavel, Rudenko, Igor, Konstantynovskyi, Oleksandr, Vaičiukynienė, Danutė
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9104729/
https://www.ncbi.nlm.nih.gov/pubmed/35591338
http://dx.doi.org/10.3390/ma15093003
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author Krivenko, Pavel
Rudenko, Igor
Konstantynovskyi, Oleksandr
Vaičiukynienė, Danutė
author_facet Krivenko, Pavel
Rudenko, Igor
Konstantynovskyi, Oleksandr
Vaičiukynienė, Danutė
author_sort Krivenko, Pavel
collection PubMed
description The use of blast furnace cement is an effective way to meet the requirements of sustainable development. However, CEM III/C is characterized by slow strength gain. The problem can be worse for plasticized reinforced blast furnace cement concretes mixed with sea water in view of shorter durability. The mitigation of corrosion in plasticized blast furnace cement concretes mixed with sea water can be provided through a composition of minor additional constituents, with percentage by mass of the main constituents: alkali metal compounds, 2…3; calcium aluminate cement, 1; clinoptilolite, 1. The alkali metal compounds are known to activate hydraulic properties of ground granulated blast furnace slag. A calcium aluminate cement promotes the accelerated chemical binding of Cl(−) and SO(4)(2−)-ions with the formation of Kuzel’s salt. A clinoptilolite occludes these aggressive ions. The positive effects of the mentioned minor additional constituents in the blast furnace cement were supported by the increased early strength gain and the higher structural density, as well as by a good state of steel reinforcement, in the plasticized concretes mixed with sea water.
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spelling pubmed-91047292022-05-14 Mitigation of Corrosion Initiated by Cl(−) and SO(4)(2−)-ions in Blast Furnace Cement Concrete Mixed with Sea Water Krivenko, Pavel Rudenko, Igor Konstantynovskyi, Oleksandr Vaičiukynienė, Danutė Materials (Basel) Article The use of blast furnace cement is an effective way to meet the requirements of sustainable development. However, CEM III/C is characterized by slow strength gain. The problem can be worse for plasticized reinforced blast furnace cement concretes mixed with sea water in view of shorter durability. The mitigation of corrosion in plasticized blast furnace cement concretes mixed with sea water can be provided through a composition of minor additional constituents, with percentage by mass of the main constituents: alkali metal compounds, 2…3; calcium aluminate cement, 1; clinoptilolite, 1. The alkali metal compounds are known to activate hydraulic properties of ground granulated blast furnace slag. A calcium aluminate cement promotes the accelerated chemical binding of Cl(−) and SO(4)(2−)-ions with the formation of Kuzel’s salt. A clinoptilolite occludes these aggressive ions. The positive effects of the mentioned minor additional constituents in the blast furnace cement were supported by the increased early strength gain and the higher structural density, as well as by a good state of steel reinforcement, in the plasticized concretes mixed with sea water. MDPI 2022-04-20 /pmc/articles/PMC9104729/ /pubmed/35591338 http://dx.doi.org/10.3390/ma15093003 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Krivenko, Pavel
Rudenko, Igor
Konstantynovskyi, Oleksandr
Vaičiukynienė, Danutė
Mitigation of Corrosion Initiated by Cl(−) and SO(4)(2−)-ions in Blast Furnace Cement Concrete Mixed with Sea Water
title Mitigation of Corrosion Initiated by Cl(−) and SO(4)(2−)-ions in Blast Furnace Cement Concrete Mixed with Sea Water
title_full Mitigation of Corrosion Initiated by Cl(−) and SO(4)(2−)-ions in Blast Furnace Cement Concrete Mixed with Sea Water
title_fullStr Mitigation of Corrosion Initiated by Cl(−) and SO(4)(2−)-ions in Blast Furnace Cement Concrete Mixed with Sea Water
title_full_unstemmed Mitigation of Corrosion Initiated by Cl(−) and SO(4)(2−)-ions in Blast Furnace Cement Concrete Mixed with Sea Water
title_short Mitigation of Corrosion Initiated by Cl(−) and SO(4)(2−)-ions in Blast Furnace Cement Concrete Mixed with Sea Water
title_sort mitigation of corrosion initiated by cl(−) and so(4)(2−)-ions in blast furnace cement concrete mixed with sea water
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9104729/
https://www.ncbi.nlm.nih.gov/pubmed/35591338
http://dx.doi.org/10.3390/ma15093003
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