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Experimental Investigation of the High-Temperature Rheological and Aging Resistance Properties of Activated Crumb Rubber Powder/SBS Composite-Modified Asphalt

Crumb rubber could form the active groups on the surface by interrupting the crosslinking bond to improve the compatibility with asphalt. While styrene-butadiene-styrene block copolymer (SBS)-modified asphalt has excellent comprehensive properties, it has poor anti-aging performance and a high cost....

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Autores principales: Zhao, Zhizhong, Wang, Longlin, Wang, Wensheng, Shangguan, Xuanhao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9105231/
https://www.ncbi.nlm.nih.gov/pubmed/35567074
http://dx.doi.org/10.3390/polym14091905
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author Zhao, Zhizhong
Wang, Longlin
Wang, Wensheng
Shangguan, Xuanhao
author_facet Zhao, Zhizhong
Wang, Longlin
Wang, Wensheng
Shangguan, Xuanhao
author_sort Zhao, Zhizhong
collection PubMed
description Crumb rubber could form the active groups on the surface by interrupting the crosslinking bond to improve the compatibility with asphalt. While styrene-butadiene-styrene block copolymer (SBS)-modified asphalt has excellent comprehensive properties, it has poor anti-aging performance and a high cost. To explore the influence of composite modification of activated crumb rubber powder (ACR) and SBS on asphalt, modified asphalt samples with different modifiers and SBS contents were prepared. Conventional physical properties tests, a dynamic shear rheometer (DSR), and the thin-film oven test (TFOT) were used to study the conventional physical properties, high-temperature rheological properties, and aging resistance of asphalt. In addition, the action forms and distribution of modifiers in asphalt were observed by an optical microscope to characterize the micro-morphology of ACR/SBS composite-modified asphalt. Test results showed that after adding SBS, the softening point, ductility, and elastic recovery of ACR/SBS asphalt could be significantly improved, but the viscosity and softening point difference were also larger. At the same time, according to the complex shear modulus, phase angle, and rutting factor, SBS can effectively improve the high-temperature deformation resistance of ACR/SBS asphalt. The modified asphalt (ACR/SBS-2) had good high- and low- temperature performances, as well as an appropriate viscosity and low softening point difference, as a research object of aging. After short-term aging, the changes in the high- and low-temperature performances and workability of ACR/SBS asphalt were reduced. Taking the softening point as the target performance, the softening point of ACR/SBS asphalt was less affected by aging time and temperature, indicating that ACR/SBS asphalt was not sensitive to aging temperature and had good stability and aging resistance. From the micrograph by microscope, it was found that ACR/SBS asphalt could maintain a relatively stable polyphase structure for aging resistance.
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spelling pubmed-91052312022-05-14 Experimental Investigation of the High-Temperature Rheological and Aging Resistance Properties of Activated Crumb Rubber Powder/SBS Composite-Modified Asphalt Zhao, Zhizhong Wang, Longlin Wang, Wensheng Shangguan, Xuanhao Polymers (Basel) Article Crumb rubber could form the active groups on the surface by interrupting the crosslinking bond to improve the compatibility with asphalt. While styrene-butadiene-styrene block copolymer (SBS)-modified asphalt has excellent comprehensive properties, it has poor anti-aging performance and a high cost. To explore the influence of composite modification of activated crumb rubber powder (ACR) and SBS on asphalt, modified asphalt samples with different modifiers and SBS contents were prepared. Conventional physical properties tests, a dynamic shear rheometer (DSR), and the thin-film oven test (TFOT) were used to study the conventional physical properties, high-temperature rheological properties, and aging resistance of asphalt. In addition, the action forms and distribution of modifiers in asphalt were observed by an optical microscope to characterize the micro-morphology of ACR/SBS composite-modified asphalt. Test results showed that after adding SBS, the softening point, ductility, and elastic recovery of ACR/SBS asphalt could be significantly improved, but the viscosity and softening point difference were also larger. At the same time, according to the complex shear modulus, phase angle, and rutting factor, SBS can effectively improve the high-temperature deformation resistance of ACR/SBS asphalt. The modified asphalt (ACR/SBS-2) had good high- and low- temperature performances, as well as an appropriate viscosity and low softening point difference, as a research object of aging. After short-term aging, the changes in the high- and low-temperature performances and workability of ACR/SBS asphalt were reduced. Taking the softening point as the target performance, the softening point of ACR/SBS asphalt was less affected by aging time and temperature, indicating that ACR/SBS asphalt was not sensitive to aging temperature and had good stability and aging resistance. From the micrograph by microscope, it was found that ACR/SBS asphalt could maintain a relatively stable polyphase structure for aging resistance. MDPI 2022-05-06 /pmc/articles/PMC9105231/ /pubmed/35567074 http://dx.doi.org/10.3390/polym14091905 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zhao, Zhizhong
Wang, Longlin
Wang, Wensheng
Shangguan, Xuanhao
Experimental Investigation of the High-Temperature Rheological and Aging Resistance Properties of Activated Crumb Rubber Powder/SBS Composite-Modified Asphalt
title Experimental Investigation of the High-Temperature Rheological and Aging Resistance Properties of Activated Crumb Rubber Powder/SBS Composite-Modified Asphalt
title_full Experimental Investigation of the High-Temperature Rheological and Aging Resistance Properties of Activated Crumb Rubber Powder/SBS Composite-Modified Asphalt
title_fullStr Experimental Investigation of the High-Temperature Rheological and Aging Resistance Properties of Activated Crumb Rubber Powder/SBS Composite-Modified Asphalt
title_full_unstemmed Experimental Investigation of the High-Temperature Rheological and Aging Resistance Properties of Activated Crumb Rubber Powder/SBS Composite-Modified Asphalt
title_short Experimental Investigation of the High-Temperature Rheological and Aging Resistance Properties of Activated Crumb Rubber Powder/SBS Composite-Modified Asphalt
title_sort experimental investigation of the high-temperature rheological and aging resistance properties of activated crumb rubber powder/sbs composite-modified asphalt
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9105231/
https://www.ncbi.nlm.nih.gov/pubmed/35567074
http://dx.doi.org/10.3390/polym14091905
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