Pd-containing magnetic periodic mesoporous organosilica nanocomposite as an efficient and highly recoverable catalyst

A novel magnetic ionic liquid based periodic mesoporous organosilica supported palladium (Fe(3)O(4)@SiO(2)@IL-PMO/Pd) nanocomposite is synthesized, characterized and its catalytic performance is investigated in the Heck reaction. The Fe(3)O(4)@SiO(2)@IL-PMO/Pd nanocatalyst was characterized using FT...

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Autores principales: Neysi, Maryam, Elhamifar, Dawood
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9106672/
https://www.ncbi.nlm.nih.gov/pubmed/35562531
http://dx.doi.org/10.1038/s41598-022-11918-x
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author Neysi, Maryam
Elhamifar, Dawood
author_facet Neysi, Maryam
Elhamifar, Dawood
author_sort Neysi, Maryam
collection PubMed
description A novel magnetic ionic liquid based periodic mesoporous organosilica supported palladium (Fe(3)O(4)@SiO(2)@IL-PMO/Pd) nanocomposite is synthesized, characterized and its catalytic performance is investigated in the Heck reaction. The Fe(3)O(4)@SiO(2)@IL-PMO/Pd nanocatalyst was characterized using FT-IR, PXRD, SEM, TEM, VSM, TG, nitrogen-sorption and EDX analyses. This nanocomposite was effectively employed as catalyst in the Heck reaction to give corresponding arylalkenes in high yield. The recovery test was performed to study the catalyst stability and durability under applied conditions.
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spelling pubmed-91066722022-05-15 Pd-containing magnetic periodic mesoporous organosilica nanocomposite as an efficient and highly recoverable catalyst Neysi, Maryam Elhamifar, Dawood Sci Rep Article A novel magnetic ionic liquid based periodic mesoporous organosilica supported palladium (Fe(3)O(4)@SiO(2)@IL-PMO/Pd) nanocomposite is synthesized, characterized and its catalytic performance is investigated in the Heck reaction. The Fe(3)O(4)@SiO(2)@IL-PMO/Pd nanocatalyst was characterized using FT-IR, PXRD, SEM, TEM, VSM, TG, nitrogen-sorption and EDX analyses. This nanocomposite was effectively employed as catalyst in the Heck reaction to give corresponding arylalkenes in high yield. The recovery test was performed to study the catalyst stability and durability under applied conditions. Nature Publishing Group UK 2022-05-13 /pmc/articles/PMC9106672/ /pubmed/35562531 http://dx.doi.org/10.1038/s41598-022-11918-x Text en © The Author(s) 2022 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Neysi, Maryam
Elhamifar, Dawood
Pd-containing magnetic periodic mesoporous organosilica nanocomposite as an efficient and highly recoverable catalyst
title Pd-containing magnetic periodic mesoporous organosilica nanocomposite as an efficient and highly recoverable catalyst
title_full Pd-containing magnetic periodic mesoporous organosilica nanocomposite as an efficient and highly recoverable catalyst
title_fullStr Pd-containing magnetic periodic mesoporous organosilica nanocomposite as an efficient and highly recoverable catalyst
title_full_unstemmed Pd-containing magnetic periodic mesoporous organosilica nanocomposite as an efficient and highly recoverable catalyst
title_short Pd-containing magnetic periodic mesoporous organosilica nanocomposite as an efficient and highly recoverable catalyst
title_sort pd-containing magnetic periodic mesoporous organosilica nanocomposite as an efficient and highly recoverable catalyst
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9106672/
https://www.ncbi.nlm.nih.gov/pubmed/35562531
http://dx.doi.org/10.1038/s41598-022-11918-x
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