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Ni(2+)‐Directed Anisotropic Growth of PtCu Nested Skeleton Cubes Boosting Electroreduction of Oxygen

Structure‐controlled Pt‐based nanocrystals have the great potential to provide a flexible strategy for improving the catalysis of the oxygen reduction reaction (ORR). Here, a new synthetic approach is developed to tune the 3D structure of Pt‐based alloys, and switch a synthetic reaction which produc...

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Autores principales: Zhang, Yafeng, Ye, Kai, Liu, Qianru, Qin, Juan, Jiang, Qike, Yang, Bing, Yin, Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9108632/
https://www.ncbi.nlm.nih.gov/pubmed/35266308
http://dx.doi.org/10.1002/advs.202104927
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author Zhang, Yafeng
Ye, Kai
Liu, Qianru
Qin, Juan
Jiang, Qike
Yang, Bing
Yin, Feng
author_facet Zhang, Yafeng
Ye, Kai
Liu, Qianru
Qin, Juan
Jiang, Qike
Yang, Bing
Yin, Feng
author_sort Zhang, Yafeng
collection PubMed
description Structure‐controlled Pt‐based nanocrystals have the great potential to provide a flexible strategy for improving the catalysis of the oxygen reduction reaction (ORR). Here, a new synthetic approach is developed to tune the 3D structure of Pt‐based alloys, and switch a synthetic reaction which produces solid PtCu octahedral stars (OSs) to produce PtCu nested skeleton cubes (NSCs) by simple addition of Ni(acac)(2). In particular, Ni(2+)‐guided anisotropic growth is observed to generate the nested skeleton structure in PtCu NSCs. Ni(2+), though absent from the nanoalloys, not only endows faster Cu reduction kinetics but also acts as a structure‐directing agent. Moreover, it is shown that acetic acid treatment of PtCu NSCs/C exposes Pt‐rich surface with a fine‐tuned Pt d‐band center energy and the reduced Cu leaching, resulting in strikingly high activity and stability. Acid‐treated PtCu NSCs/C shows a remarkable ORR mass activity of 5.13 A mg(Pt) (–1), about 26 times higher than commercial Pt/C catalyst. This catalyst also exhibits excellent stability with a lower activity decay of 11.5% and the negligible variation in structure after 10 000 cycles.
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spelling pubmed-91086322022-05-20 Ni(2+)‐Directed Anisotropic Growth of PtCu Nested Skeleton Cubes Boosting Electroreduction of Oxygen Zhang, Yafeng Ye, Kai Liu, Qianru Qin, Juan Jiang, Qike Yang, Bing Yin, Feng Adv Sci (Weinh) Research Articles Structure‐controlled Pt‐based nanocrystals have the great potential to provide a flexible strategy for improving the catalysis of the oxygen reduction reaction (ORR). Here, a new synthetic approach is developed to tune the 3D structure of Pt‐based alloys, and switch a synthetic reaction which produces solid PtCu octahedral stars (OSs) to produce PtCu nested skeleton cubes (NSCs) by simple addition of Ni(acac)(2). In particular, Ni(2+)‐guided anisotropic growth is observed to generate the nested skeleton structure in PtCu NSCs. Ni(2+), though absent from the nanoalloys, not only endows faster Cu reduction kinetics but also acts as a structure‐directing agent. Moreover, it is shown that acetic acid treatment of PtCu NSCs/C exposes Pt‐rich surface with a fine‐tuned Pt d‐band center energy and the reduced Cu leaching, resulting in strikingly high activity and stability. Acid‐treated PtCu NSCs/C shows a remarkable ORR mass activity of 5.13 A mg(Pt) (–1), about 26 times higher than commercial Pt/C catalyst. This catalyst also exhibits excellent stability with a lower activity decay of 11.5% and the negligible variation in structure after 10 000 cycles. John Wiley and Sons Inc. 2022-03-10 /pmc/articles/PMC9108632/ /pubmed/35266308 http://dx.doi.org/10.1002/advs.202104927 Text en © 2022 The Authors. Advanced Science published by Wiley‐VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Articles
Zhang, Yafeng
Ye, Kai
Liu, Qianru
Qin, Juan
Jiang, Qike
Yang, Bing
Yin, Feng
Ni(2+)‐Directed Anisotropic Growth of PtCu Nested Skeleton Cubes Boosting Electroreduction of Oxygen
title Ni(2+)‐Directed Anisotropic Growth of PtCu Nested Skeleton Cubes Boosting Electroreduction of Oxygen
title_full Ni(2+)‐Directed Anisotropic Growth of PtCu Nested Skeleton Cubes Boosting Electroreduction of Oxygen
title_fullStr Ni(2+)‐Directed Anisotropic Growth of PtCu Nested Skeleton Cubes Boosting Electroreduction of Oxygen
title_full_unstemmed Ni(2+)‐Directed Anisotropic Growth of PtCu Nested Skeleton Cubes Boosting Electroreduction of Oxygen
title_short Ni(2+)‐Directed Anisotropic Growth of PtCu Nested Skeleton Cubes Boosting Electroreduction of Oxygen
title_sort ni(2+)‐directed anisotropic growth of ptcu nested skeleton cubes boosting electroreduction of oxygen
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9108632/
https://www.ncbi.nlm.nih.gov/pubmed/35266308
http://dx.doi.org/10.1002/advs.202104927
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