Unusual highly diastereoselective Rh(II)-catalyzed dimerization of 3-diazo-2-arylidenesuccinimides provides access to a new dibenzazulene scaffold

Formation of unusual unsymmetrical dimers or/and indenes via Rh(2)(esp)(2)-catalyzed decomposition of 3-diazo-2-arylidenesuccinimides has been investigated. The reaction proceeded under mild conditions, and its result was shown to strongly depend on the nature of the substituents in the diazo substr...

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Detalles Bibliográficos
Autores principales: Vepreva, Anastasia, Bunev, Alexander S, Kudinov, Andrey Yu, Kantin, Grigory, Krasavin, Mikhail, Dar’in, Dmitry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2022
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9112184/
https://www.ncbi.nlm.nih.gov/pubmed/35615536
http://dx.doi.org/10.3762/bjoc.18.55

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9112184/
https://www.ncbi.nlm.nih.gov/pubmed/35615536
http://dx.doi.org/10.3762/bjoc.18.55

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