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Generation of a transient base-stabilised arylalumylene for the facile deconstruction of aromatic molecules

While a stable base-free arylalumylene bearing a sterically encumbered terphenyl substituent has been reported previously, we herein report that our attempts to form a base-stabilised arylalumylene bearing a relatively small terphenyl substituent and an N-heterocyclic carbene base led instead to a “...

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Detalles Bibliográficos
Autores principales: Dhara, Debabrata, Jayaraman, Arumugam, Härterich, Marcel, Dewhurst, Rian D., Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9116349/
https://www.ncbi.nlm.nih.gov/pubmed/35694334
http://dx.doi.org/10.1039/d2sc01436j