Photocatalytic C(sp(3)) radical generation via C–H, C–C, and C–X bond cleavage

C(sp(3)) radicals (R˙) are of broad research interest and synthetic utility. This review collects some of the most recent advancements in photocatalytic R˙ generation and highlights representative examples in this field. Based on the key bond cleavages that generate R˙, these contributions are divid...

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Autores principales: Huang, Chia-Yu, Li, Jianbin, Li, Chao-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9116372/
https://www.ncbi.nlm.nih.gov/pubmed/35694342
http://dx.doi.org/10.1039/d2sc00202g
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author Huang, Chia-Yu
Li, Jianbin
Li, Chao-Jun
author_facet Huang, Chia-Yu
Li, Jianbin
Li, Chao-Jun
author_sort Huang, Chia-Yu
collection PubMed
description C(sp(3)) radicals (R˙) are of broad research interest and synthetic utility. This review collects some of the most recent advancements in photocatalytic R˙ generation and highlights representative examples in this field. Based on the key bond cleavages that generate R˙, these contributions are divided into C–H, C–C, and C–X bond cleavages. A general mechanistic scenario and key R˙-forming steps are presented and discussed in each section.
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spelling pubmed-91163722022-06-10 Photocatalytic C(sp(3)) radical generation via C–H, C–C, and C–X bond cleavage Huang, Chia-Yu Li, Jianbin Li, Chao-Jun Chem Sci Chemistry C(sp(3)) radicals (R˙) are of broad research interest and synthetic utility. This review collects some of the most recent advancements in photocatalytic R˙ generation and highlights representative examples in this field. Based on the key bond cleavages that generate R˙, these contributions are divided into C–H, C–C, and C–X bond cleavages. A general mechanistic scenario and key R˙-forming steps are presented and discussed in each section. The Royal Society of Chemistry 2022-04-18 /pmc/articles/PMC9116372/ /pubmed/35694342 http://dx.doi.org/10.1039/d2sc00202g Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Huang, Chia-Yu
Li, Jianbin
Li, Chao-Jun
Photocatalytic C(sp(3)) radical generation via C–H, C–C, and C–X bond cleavage
title Photocatalytic C(sp(3)) radical generation via C–H, C–C, and C–X bond cleavage
title_full Photocatalytic C(sp(3)) radical generation via C–H, C–C, and C–X bond cleavage
title_fullStr Photocatalytic C(sp(3)) radical generation via C–H, C–C, and C–X bond cleavage
title_full_unstemmed Photocatalytic C(sp(3)) radical generation via C–H, C–C, and C–X bond cleavage
title_short Photocatalytic C(sp(3)) radical generation via C–H, C–C, and C–X bond cleavage
title_sort photocatalytic c(sp(3)) radical generation via c–h, c–c, and c–x bond cleavage
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9116372/
https://www.ncbi.nlm.nih.gov/pubmed/35694342
http://dx.doi.org/10.1039/d2sc00202g
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AT lijianbin photocatalyticcsp3radicalgenerationviachccandcxbondcleavage
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