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Polymerization kinetics of bicyclic olefins and mechanism with symmetrical ansa-metallocene catalysts associated with active center count: relationship between their activities and structure and activation path
Copolymerization of ethylene (E) with 5-vinyl-2-norbornene (VNB) catalyzed by ansa-metallocenes allows the precise control of essential polymeric properties such as comonomer incorporation, molecular weight (M(w)), and polydispersity (Đ). Significant efforts have been devoted to synthesizing and dev...
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9118019/ https://www.ncbi.nlm.nih.gov/pubmed/35693231 http://dx.doi.org/10.1039/d2ra01264b |