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Effect of Moisture on Methane Adsorption Characteristics of Long-Flame Coal

[Image: see text] Long-flame coal is a bituminous coal with the lowest metamorphic degree, accounting for 16.1% of China’s coal reserves. With increases in mining depths and intensities, mine gas disasters related to the mining of long-flame coal are becoming increasingly serious. Therefore, the exp...

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Autores principales: Chen, Xiangjun, Wang, Xiaodan, Zhao, San, Kang, Ningning, Feng, Shuailong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9118383/
https://www.ncbi.nlm.nih.gov/pubmed/35601315
http://dx.doi.org/10.1021/acsomega.2c01144
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author Chen, Xiangjun
Wang, Xiaodan
Zhao, San
Kang, Ningning
Feng, Shuailong
author_facet Chen, Xiangjun
Wang, Xiaodan
Zhao, San
Kang, Ningning
Feng, Shuailong
author_sort Chen, Xiangjun
collection PubMed
description [Image: see text] Long-flame coal is a bituminous coal with the lowest metamorphic degree, accounting for 16.1% of China’s coal reserves. With increases in mining depths and intensities, mine gas disasters related to the mining of long-flame coal are becoming increasingly serious. Therefore, the exploration of the effect of moisture on the adsorption of methane in coal can provide support for popularizing the application of hydraulic measures in long-flame coal mining areas. In this paper, a molecular structure model of long-flame coal was established by molecular dynamics and the Monte Carlo method. The adsorption characteristics of methane in long-flame coal structures under different pressures were simulated, and the effects of different amounts of water on the methane adsorption and adsorption heat were explored. The results show that, under the same adsorption equilibrium pressure, the methane adsorption rate decreases with increasing water content, and with increasing adsorption equilibrium pressure, the adsorption capacity of methane increases gradually; this increasing trend is in agreement with the Langmuir equation. The water adsorption of coal is greater than the methane adsorption of coal. With the increase in the number of water molecules, when coal-based molecules adsorb methane and then adsorb water molecules, the adsorption heat of methane is reduced, and the desorption of methane molecules is promoted.
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spelling pubmed-91183832022-05-20 Effect of Moisture on Methane Adsorption Characteristics of Long-Flame Coal Chen, Xiangjun Wang, Xiaodan Zhao, San Kang, Ningning Feng, Shuailong ACS Omega [Image: see text] Long-flame coal is a bituminous coal with the lowest metamorphic degree, accounting for 16.1% of China’s coal reserves. With increases in mining depths and intensities, mine gas disasters related to the mining of long-flame coal are becoming increasingly serious. Therefore, the exploration of the effect of moisture on the adsorption of methane in coal can provide support for popularizing the application of hydraulic measures in long-flame coal mining areas. In this paper, a molecular structure model of long-flame coal was established by molecular dynamics and the Monte Carlo method. The adsorption characteristics of methane in long-flame coal structures under different pressures were simulated, and the effects of different amounts of water on the methane adsorption and adsorption heat were explored. The results show that, under the same adsorption equilibrium pressure, the methane adsorption rate decreases with increasing water content, and with increasing adsorption equilibrium pressure, the adsorption capacity of methane increases gradually; this increasing trend is in agreement with the Langmuir equation. The water adsorption of coal is greater than the methane adsorption of coal. With the increase in the number of water molecules, when coal-based molecules adsorb methane and then adsorb water molecules, the adsorption heat of methane is reduced, and the desorption of methane molecules is promoted. American Chemical Society 2022-05-05 /pmc/articles/PMC9118383/ /pubmed/35601315 http://dx.doi.org/10.1021/acsomega.2c01144 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Chen, Xiangjun
Wang, Xiaodan
Zhao, San
Kang, Ningning
Feng, Shuailong
Effect of Moisture on Methane Adsorption Characteristics of Long-Flame Coal
title Effect of Moisture on Methane Adsorption Characteristics of Long-Flame Coal
title_full Effect of Moisture on Methane Adsorption Characteristics of Long-Flame Coal
title_fullStr Effect of Moisture on Methane Adsorption Characteristics of Long-Flame Coal
title_full_unstemmed Effect of Moisture on Methane Adsorption Characteristics of Long-Flame Coal
title_short Effect of Moisture on Methane Adsorption Characteristics of Long-Flame Coal
title_sort effect of moisture on methane adsorption characteristics of long-flame coal
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9118383/
https://www.ncbi.nlm.nih.gov/pubmed/35601315
http://dx.doi.org/10.1021/acsomega.2c01144
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