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Imine-Linked Covalent Organic Framework with a Naphthalene Moiety as a Sensitive Phosphate Ion Sensing

[Image: see text] Due to the excellent ion-sensing potential of covalent organic frameworks (COFs), the new imine-linked conjugated COF (IC-COF) is synthesized through a water-based synthesis reaction between 1,5-diaminonaphthalene and 2,4,6-tris(4-formylphenoxy)-1,3,5-triazine to create a luminesce...

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Autores principales: Afshari, Mohaddeseh, Dinari, Mohammad, Farrokhpour, Hossein, Zamora, Félix
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9121346/
https://www.ncbi.nlm.nih.gov/pubmed/35503993
http://dx.doi.org/10.1021/acsami.1c24555
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author Afshari, Mohaddeseh
Dinari, Mohammad
Farrokhpour, Hossein
Zamora, Félix
author_facet Afshari, Mohaddeseh
Dinari, Mohammad
Farrokhpour, Hossein
Zamora, Félix
author_sort Afshari, Mohaddeseh
collection PubMed
description [Image: see text] Due to the excellent ion-sensing potential of covalent organic frameworks (COFs), the new imine-linked conjugated COF (IC-COF) is synthesized through a water-based synthesis reaction between 1,5-diaminonaphthalene and 2,4,6-tris(4-formylphenoxy)-1,3,5-triazine to create a luminescence sensor. It is noteworthy that the green synthesized IC-COF shows excellent selectivity to phosphate ions (PO(4)(3–)) with a detection limit of 0.61 μM. The recyclability performance of IC-COF is high, indicating that it can be reused without a significant reduction in performance (5.2% decline after 5 cycles). Theoretical calculations using the density functional theory are performed on the IC-COF–PO(4)(3–) and IC-COF–Cu(+) complexes to explore the sensing mechanism. The fluorescence quenching in the presence of PO(4)(3–) ions is attributed to the difference between PO(4)(3–) binding sites to the IC-COF compared to Cu(+), which leads to the considerable change in the IC-COF absorption spectrum from 400 to 600 nm.
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spelling pubmed-91213462022-05-21 Imine-Linked Covalent Organic Framework with a Naphthalene Moiety as a Sensitive Phosphate Ion Sensing Afshari, Mohaddeseh Dinari, Mohammad Farrokhpour, Hossein Zamora, Félix ACS Appl Mater Interfaces [Image: see text] Due to the excellent ion-sensing potential of covalent organic frameworks (COFs), the new imine-linked conjugated COF (IC-COF) is synthesized through a water-based synthesis reaction between 1,5-diaminonaphthalene and 2,4,6-tris(4-formylphenoxy)-1,3,5-triazine to create a luminescence sensor. It is noteworthy that the green synthesized IC-COF shows excellent selectivity to phosphate ions (PO(4)(3–)) with a detection limit of 0.61 μM. The recyclability performance of IC-COF is high, indicating that it can be reused without a significant reduction in performance (5.2% decline after 5 cycles). Theoretical calculations using the density functional theory are performed on the IC-COF–PO(4)(3–) and IC-COF–Cu(+) complexes to explore the sensing mechanism. The fluorescence quenching in the presence of PO(4)(3–) ions is attributed to the difference between PO(4)(3–) binding sites to the IC-COF compared to Cu(+), which leads to the considerable change in the IC-COF absorption spectrum from 400 to 600 nm. American Chemical Society 2022-05-03 2022-05-18 /pmc/articles/PMC9121346/ /pubmed/35503993 http://dx.doi.org/10.1021/acsami.1c24555 Text en © 2022 American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Afshari, Mohaddeseh
Dinari, Mohammad
Farrokhpour, Hossein
Zamora, Félix
Imine-Linked Covalent Organic Framework with a Naphthalene Moiety as a Sensitive Phosphate Ion Sensing
title Imine-Linked Covalent Organic Framework with a Naphthalene Moiety as a Sensitive Phosphate Ion Sensing
title_full Imine-Linked Covalent Organic Framework with a Naphthalene Moiety as a Sensitive Phosphate Ion Sensing
title_fullStr Imine-Linked Covalent Organic Framework with a Naphthalene Moiety as a Sensitive Phosphate Ion Sensing
title_full_unstemmed Imine-Linked Covalent Organic Framework with a Naphthalene Moiety as a Sensitive Phosphate Ion Sensing
title_short Imine-Linked Covalent Organic Framework with a Naphthalene Moiety as a Sensitive Phosphate Ion Sensing
title_sort imine-linked covalent organic framework with a naphthalene moiety as a sensitive phosphate ion sensing
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9121346/
https://www.ncbi.nlm.nih.gov/pubmed/35503993
http://dx.doi.org/10.1021/acsami.1c24555
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