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Identification of seven-coordinate Ln(III) ions in a Ln(III)[15-MC(Fe)(III)(N(shi))-5](OAc)(2)Cl species crystallized from methanol and pyridine
The title metallacrown (MC) complexes Ln(III)[15-MC(Fe(III)N(shi))-5](OAc)(2)CI(C(5)H(5)N)(6) (Ln1), where OAc(−) is acetate, shi(3−) is salicylhydroximate, and Ln = Gd and Dy, were synthesized via a self-assembly reaction in methanol and pyridine. Single crystals were grown using slow evaporation a...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9122301/ https://www.ncbi.nlm.nih.gov/pubmed/35602264 http://dx.doi.org/10.1007/s10870-021-00900-6 |