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Strengthened second law for multi-dimensional systems coupled to multiple thermodynamic reservoirs

The second law of thermodynamics can be formulated as a restriction on the evolution of the entropy of any system undergoing Markovian dynamics. Here I show that this form of the second law is strengthened for multi-dimensional, complex systems, coupled to multiple thermodynamic reservoirs, if we ha...

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Autor principal: Wolpert, David H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9125225/
https://www.ncbi.nlm.nih.gov/pubmed/35599569
http://dx.doi.org/10.1098/rsta.2020.0428
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author Wolpert, David H.
author_facet Wolpert, David H.
author_sort Wolpert, David H.
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description The second law of thermodynamics can be formulated as a restriction on the evolution of the entropy of any system undergoing Markovian dynamics. Here I show that this form of the second law is strengthened for multi-dimensional, complex systems, coupled to multiple thermodynamic reservoirs, if we have a set of a priori constraints restricting how the dynamics of each coordinate can depend on the other coordinates. As an example, this strengthened second law (SSL) applies to complex systems composed of multiple physically separated, co-evolving subsystems, each identified as a coordinate of the overall system. In this example, the constraints concern how the dynamics of some subsystems are allowed to depend on the states of the other subsystems. Importantly, the SSL applies to such complex systems even if some of its subsystems can change state simultaneously, which is prohibited in a multipartite process. The SSL also strengthens previously derived bounds on how much work can be extracted from a system using feedback control, if the system is multi-dimensional. Importantly, the SSL does not require local detailed balance. So it potentially applies to complex systems ranging from interacting economic agents to co-evolving biological species. This article is part of the theme issue ‘Emergent phenomena in complex physical and socio-technical systems: from cells to societies’.
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spelling pubmed-91252252022-05-27 Strengthened second law for multi-dimensional systems coupled to multiple thermodynamic reservoirs Wolpert, David H. Philos Trans A Math Phys Eng Sci Articles The second law of thermodynamics can be formulated as a restriction on the evolution of the entropy of any system undergoing Markovian dynamics. Here I show that this form of the second law is strengthened for multi-dimensional, complex systems, coupled to multiple thermodynamic reservoirs, if we have a set of a priori constraints restricting how the dynamics of each coordinate can depend on the other coordinates. As an example, this strengthened second law (SSL) applies to complex systems composed of multiple physically separated, co-evolving subsystems, each identified as a coordinate of the overall system. In this example, the constraints concern how the dynamics of some subsystems are allowed to depend on the states of the other subsystems. Importantly, the SSL applies to such complex systems even if some of its subsystems can change state simultaneously, which is prohibited in a multipartite process. The SSL also strengthens previously derived bounds on how much work can be extracted from a system using feedback control, if the system is multi-dimensional. Importantly, the SSL does not require local detailed balance. So it potentially applies to complex systems ranging from interacting economic agents to co-evolving biological species. This article is part of the theme issue ‘Emergent phenomena in complex physical and socio-technical systems: from cells to societies’. The Royal Society 2022-07-11 2022-05-23 /pmc/articles/PMC9125225/ /pubmed/35599569 http://dx.doi.org/10.1098/rsta.2020.0428 Text en © 2022 The Authors. https://creativecommons.org/licenses/by/4.0/Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) , which permits unrestricted use, provided the original author and source are credited.
spellingShingle Articles
Wolpert, David H.
Strengthened second law for multi-dimensional systems coupled to multiple thermodynamic reservoirs
title Strengthened second law for multi-dimensional systems coupled to multiple thermodynamic reservoirs
title_full Strengthened second law for multi-dimensional systems coupled to multiple thermodynamic reservoirs
title_fullStr Strengthened second law for multi-dimensional systems coupled to multiple thermodynamic reservoirs
title_full_unstemmed Strengthened second law for multi-dimensional systems coupled to multiple thermodynamic reservoirs
title_short Strengthened second law for multi-dimensional systems coupled to multiple thermodynamic reservoirs
title_sort strengthened second law for multi-dimensional systems coupled to multiple thermodynamic reservoirs
topic Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9125225/
https://www.ncbi.nlm.nih.gov/pubmed/35599569
http://dx.doi.org/10.1098/rsta.2020.0428
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