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Laboratory IR Spectra of the Ionic Oxidized Fullerenes C(60)O(+) and C(60)OH(+)
[Image: see text] We present the first experimental vibrational spectra of gaseous oxidized derivatives of C(60) in protonated and radical cation forms, obtained through infrared multiple-photon dissociation spectroscopy using the FELIX free-electron laser. Neutral C(60)O has two nearly iso-energeti...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9125688/ https://www.ncbi.nlm.nih.gov/pubmed/35533303 http://dx.doi.org/10.1021/acs.jpca.2c01329 |
Sumario: | [Image: see text] We present the first experimental vibrational spectra of gaseous oxidized derivatives of C(60) in protonated and radical cation forms, obtained through infrared multiple-photon dissociation spectroscopy using the FELIX free-electron laser. Neutral C(60)O has two nearly iso-energetic isomers: the epoxide isomer in which the O atom bridges a CC bond that connects two six-membered rings and the annulene isomer in which the O atom inserts into a CC bond connecting a five- and a six-membered ring. To determine the isomer formed for C(60)O(+) in our experiment—a question that cannot be confidently answered on the basis of the DFT-computed stabilities alone—we compare our experimental IR spectra to vibrational spectra predicted by DFT calculations. We conclude that the annulene-like isomer is formed in our experiment. For C(60)OH(+), a strong OH stretch vibration observed in the 3 μm range of the spectrum immediately reveals its structure as C(60) with a hydroxyl group attached, which is further confirmed by the spectrum in the 400–1600 cm(–1) range. We compare the experimental spectra of C(60)O(+) and C(60)OH(+) to the astronomical IR emission spectrum of a fullerene-rich planetary nebula and discuss their astrophysical relevance. |
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