Synergistic Effect of Paraffin-Incorporated In(2)O(3)/ZnO Multifold Smart Glazing Composite for the Self-Cleaning and Energy-Saving Built Environment

[Image: see text] The thermal performance of window glazing requires improvement for a sustainable built environment at an acceptable cost. The current work demonstrates a multifold smart composite consisting of an optimized In(2)O(3)/ZnO–polymethyl methacrylate–paraffin composite to reduce heat exchange through the combined self-cleaning and energy-saving envelope of the smart built environment. This work has attempted to develop a smart composite coating that combines photosensitive metal oxide and phase change materials and investigate their thermal comfort performance as a glazed window. It is observed that the In(2)O(3)/ZnO (5 wt %) multifold composite film experienced better transmittance and thermal performance compared to its other wt % composite samples. Moreover, the multifold composite-coated glass integrated into a prototype glazed window was further investigated for its thermal performance, where a steady average indoor temperature of ∼30 °C was achieved when the outside temperature reached ∼55 °C, while maintaining good visibility. Interestingly, the transparency reached ∼86% at 60 °C and exhibited a hydrophobic water contact angle (WCA) of ∼138°. In contrast, a similar film exhibits ∼64% transparency at 22 °C, where the WCA becomes moderately hydrophilic (∼68°). Temperature dependency on transparency and wettability properties was examined for up to 60 cycles, resulting in excellent indoor thermal comfort. In addition, a thermal simulation study was executed for the smart multifold glazing composite. Moreover, this study offers dynamic glazing development options for energy saving in the smart built environment.