Cargando…

Facile synthesis of amides via acceptorless dehydrogenative coupling of aryl epoxides and amines

The synthesis of amides is significant in a wide variety of academic and industrial fields. We report here a new reaction, namely acceptorless dehydrogenative coupling of epoxides and amines to form amides catalyzed by ruthenium pincer complexes. Various aryl epoxides and amines smoothly convert int...

Descripción completa

Detalles Bibliográficos
Autores principales:	Liang, Yaoyu, Luo, Jie, Milstein, David
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9132053/ https://www.ncbi.nlm.nih.gov/pubmed/35685791 http://dx.doi.org/10.1039/d2sc01959k

Ejemplares similares

Acceptorless dehydrogenative synthesis of primary amides from alcohols and ammonia
por: Luo, Jie, et al.
Publicado: (2022)

Synthesis of oxalamides by acceptorless dehydrogenative coupling of ethylene glycol and amines and the reverse hydrogenation catalyzed by ruthenium
por: Zou, You-Quan, et al.
Publicado: (2020)

Synthesis of Pyrazines and Quinoxalines via Acceptorless Dehydrogenative Coupling Routes Catalyzed by Manganese Pincer Complexes
por: Daw, Prosenjit, et al.
Publicado: (2018)

Synthesis of N-aryl amines enabled by photocatalytic dehydrogenation
por: Kim, Jungwon, et al.
Publicado: (2020)

Acceptorless Dehydrogenative Coupling Using Ammonia: Direct Synthesis of N-Heteroaromatics from Diols Catalyzed by Ruthenium
por: Daw, Prosenjit, et al.
Publicado: (2018)

Iron-Catalyzed Acceptorless Dehydrogenative Coupling of Alcohols With Aromatic Diamines: Selective Synthesis of 1,2-Disubstituted Benzimidazoles
por: Putta, Ramachandra Reddy, et al.
Publicado: (2020)

Direct synthesis of amides and imines by dehydrogenative homo or cross-coupling of amines and alcohols catalyzed by Cu-MOF
por: Anbardan, Soheil Zamani, et al.
Publicado: (2021)

Selective Acceptorless Dehydrogenation of Primary Amines to Imines by Core–Shell Cobalt Nanoparticles
por: Cui, Xinjiang, et al.
Publicado: (2020)

Iron-catalyzed urea synthesis: dehydrogenative coupling of methanol and amines
por: Lane, Elizabeth M., et al.
Publicado: (2018)

Iron-based nanocatalyst for the acceptorless dehydrogenation reactions
por: Jaiswal, Garima, et al.
Publicado: (2017)

On the mechanism of acceptorless dehydrogenation of N-heterocycles catalyzed by (t)BuOK: a computational study
por: Ma, Lishuang, et al.
Publicado: (2023)

Non-metal-mediated N-oxyl radical (TEMPO)-induced acceptorless dehydrogenation of N-heterocycles via electrocatalysis
por: Hou, Huiqing, et al.
Publicado: (2022)

Versatile routes for synthesis of diarylamines through acceptorless dehydrogenative aromatization catalysis over supported gold–palladium bimetallic nanoparticles
por: Taniguchi, Kento, et al.
Publicado: (2017)

Unified synthesis of mono/bis-arylated phenols via Rh(III)-catalyzed dehydrogenative coupling
por: Wu, Qian, et al.
Publicado: (2017)

Efficient acceptorless photo-dehydrogenation of alcohols and N-heterocycles with binuclear platinum(ii) diphosphite complexes
por: Zhong, Jian-Ji, et al.
Publicado: (2019)

Synthesis of unsymmetrically substituted triarylamines via acceptorless dehydrogenative aromatization using a Pd/C and p-toluenesulfonic acid hybrid relay catalyst
por: Takayama, Satoshi, et al.
Publicado: (2020)

Identification of active catalysts for the acceptorless dehydrogenation of alcohols to carbonyls
por: Wang, Tao, et al.
Publicado: (2021)

Tertiary amine synthesis via reductive coupling of amides with Grignard reagents
por: Xie, Lan-Gui, et al.
Publicado: (2017)

Reduced Graphene Oxides as Carbocatalysts in Acceptorless Dehydrogenation of N-Heterocycles
por: Mollar-Cuni, Andrés, et al.
Publicado: (2021)

Solvent- and transition metal-free amide synthesis from phenyl esters and aryl amines
por: Rzhevskiy, Sergey A., et al.
Publicado: (2019)

Ruthenium PNN(O) Complexes: Cooperative Reactivity and Application as Catalysts for Acceptorless Dehydrogenative Coupling Reactions
por: de Boer, Sandra Y., et al.
Publicado: (2017)

Cyclometalated iridium complexes-catalyzed acceptorless dehydrogenative coupling reaction: construction of quinoline derivatives and evaluation of their antimicrobial activities
por: Shui, Hongling, et al.
Publicado: (2022)

Selective Oxidation of Glycerol via Acceptorless Dehydrogenation Driven by Ir(I)-NHC Catalysts
por: Jiménez, M. Victoria, et al.
Publicado: (2022)

Ammonolytic transfer dehydrogenation of amines and amides: a versatile method to valorize nitrogen compounds to nitriles
por: Coeck, Robin, et al.
Publicado: (2023)

Acceptorless dehydrogenation of small molecules through cooperative base metal catalysis
por: West, Julian G., et al.
Publicado: (2015)

Metal-free carbocatalyst for room temperature acceptorless dehydrogenation of N-heterocycles
por: Hu, Haitao, et al.
Publicado: (2022)

Acceptorless Dehydrogenation of Methanol to Carbon Monoxide and Hydrogen using Molecular Catalysts
por: Kaithal, Akash, et al.
Publicado: (2021)

Practical synthesis of allylic amines via nickel-catalysed multicomponent coupling of alkenes, aldehydes, and amides
por: Xiao, Wei-Guo, et al.
Publicado: (2023)

Room Temperature Acceptorless Alkane Dehydrogenation from Molecular σ-Alkane Complexes
por: McKay, Alasdair I., et al.
Publicado: (2019)

Cross-dehydrogenative coupling and oxidative-amination reactions of ethers and alcohols with aromatics and heteroaromatics
por: Lakshman, Mahesh K., et al.
Publicado: (2017)

Base-catalyzed synthesis of aryl amides from aryl azides and aldehydes
por: Xie, Sheng, et al.
Publicado: (2016)

Chemo- and Regioselective Synthesis of Acyl-Cyclohexenes by a Tandem Acceptorless Dehydrogenation-[1,5]-Hydride Shift Cascade
por: Smith, Lewis B., et al.
Publicado: (2020)

One-pot synthesis of amides via the oxidative amidation of aldehydes and amines catalyzed by a copper-MOF
por: Jamalifard, Samira, et al.
Publicado: (2019)

Cucurbit[6]uril-Supported Fe(3)O(4) Magnetic Nanoparticles Catalyzed Green and Sustainable Synthesis of 2-Substituted Benzimidazoles via Acceptorless Dehydrogenative Coupling
por: Verma, Shruti, et al.
Publicado: (2022)

Amide synthesis via nickel-catalysed reductive aminocarbonylation of aryl halides with nitroarenes
por: Cheung, Chi Wai, et al.
Publicado: (2017)

K(2)CO(3)-promoted synthesis of amides from 1-aryl-2,2,2-trifluoroethanones and amines under mild conditions
por: Zhong, Pinyong, et al.
Publicado: (2023)

Synthesis of secondary and tertiary amides without coupling agents from amines and potassium acyltrifluoroborates (KATs)
por: Schuhmacher, Anne, et al.
Publicado: (2020)

Microwave-accelerated cross-dehydrogenative-coupling (CDC) of N-(quinolin-8-yl)amides with acetone/acetonitrile under metal-free conditions
por: Zhou, Chao, et al.
Publicado: (2023)

Preparation and Degradation of Rhodium and Iridium Diolefin Catalysts for the Acceptorless and Base-Free Dehydrogenation of Secondary Alcohols
por: Buil, María L., et al.
Publicado: (2021)

Visible-Light-Promoted Iridium(III)-Catalyzed Acceptorless Dehydrogenation of N-Heterocycles at Room Temperature
por: Mejuto, Carmen, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_oqbh9otjqgiv01biksbktphf6g