One material, many possibilities via enrichment of luminescence in La(2)Zr(2)O(7):Tb(3+) nanophosphors for forensic stimuli aided applications

Engineering a single material with multidirectional applications is crucial for improving productivity, low cost, flexibility, least power consumption, etc. To achieve these requirements, novel design structures and high-performance materials are in urgent need. Lanthanide-doped nanophosphors have the greatest strengths and ability in order to tune their applications in various dimensions. However, applications of nanophosphor in latent fingerprints visualization, anti-counterfeiting, and luminescent gels/films are still in their infancy. This study demonstrated a simple strategy to enhance the luminescence of Tb(3+) (1–11 mol %) doped La(2)Zr(2)O(7) nanophosphors by conjugating various fluxes via a simple solution combustion route. The photoluminescence emission spectra reveal intense peaks at ~ 491, 546, 587, and 622 nm, which arises from (5)D(4) → (7)F(J) (J = 6, 5, 4, 3) transitions of Tb(3+) ions, respectively. The highest emission intensity was achieved in the NH(4)Cl flux assisted nanophosphor as compared to NaBr and NH(4)F assisted samples. The colorimetric images of fingerprints visualized using the optimized nanophosphor on forensic related surfaces exhibit level –III ridge details, including sweat pores, the width of the ridges, bifurcation angle, and the successive distance between sweat pores, etc. These results are decisive parameters that clearly support the statement “no two persons have ever been found to have the same fingerprints”. The anti-counterfeiting security ink was formulated using optimized nanophosphor and various patterns were designed by simple screen printing and dip pen technologies. The encoded information was decrypted only under ultraviolet 254 nm light. All the designed patterns are exhibit not just what it looks/feel like and how better it works. As a synergetic contribution of enhanced luminescence of the prepared nanophosphor, the green-emissive films were fabricated, which display excellent flexibility, uniformity, and transparency in the normal and ultraviolet 254 nm light illumination. The aforementioned results revealed that the prepared NH(4)Cl flux-assisted La(2)Zr(2)O(7): Tb(3+)(7 mol %) NPs are considered to be the best candidate for multi-dimensional applications.