Cargando…

Highly efficient, bioactive, and bifunctional sorbent p–n–p visible light heterogeneous photocatalyst utilizing ultra-fine ZnS nanoparticles embedded in a polymeric nanocomposite

This study reports the successful synthesis of a ZnS@GO@Pani polymeric nanocomposite (NC) via chemical polymerization. The product was used for simultaneous photocatalytic degradation–adsorption of malachite green (MG), a carcinogenic and widely used dye. The physicochemical properties of the prepar...

Descripción completa

Detalles Bibliográficos
Autores principales: Bagheri, Hanieh, Pasha, Mohammad Akbarzadeh, Lakouraj, Moslem Mansour, Hasantabar, Vahid, Mohseni, Mojtaba
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9134219/
https://www.ncbi.nlm.nih.gov/pubmed/35733686
http://dx.doi.org/10.1039/d2ra01810a
_version_ 1784713746062508032
author Bagheri, Hanieh
Pasha, Mohammad Akbarzadeh
Lakouraj, Moslem Mansour
Hasantabar, Vahid
Mohseni, Mojtaba
author_facet Bagheri, Hanieh
Pasha, Mohammad Akbarzadeh
Lakouraj, Moslem Mansour
Hasantabar, Vahid
Mohseni, Mojtaba
author_sort Bagheri, Hanieh
collection PubMed
description This study reports the successful synthesis of a ZnS@GO@Pani polymeric nanocomposite (NC) via chemical polymerization. The product was used for simultaneous photocatalytic degradation–adsorption of malachite green (MG), a carcinogenic and widely used dye. The physicochemical properties of the prepared NC were characterized by various techniques. Morphological and XRD results confirmed the fine size of ZnS nanoparticles (NPs) with an approximate mean size of 5 nm, uniformly distributed within the polymeric matrix. For comparative purposes, photocatalytic dye degradation–adsorption of this nanohybrid was explored both in the dark and under natural light. It was observed that 0.1 g of the ternary NC in MG aqueous solution (20 ppm) leads to dye adsorption within 15 minutes with an efficiency of 70% under dark conditions. Also, MG removal efficiency of up to 90% was achieved in 15 minutes under natural light owing to integrated photocatalytic degradation–adsorption mechanisms. Adsorption isotherm studies were performed considering Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich (D–R) models. The results showed that the Freundlich isotherm with R(2) = 0.988 is well consistent with the experimental data. Integrated photocatalytic degradation–adsorption kinetics were modeled with pseudo-first-order (PFO) and pseudo-second-order (PSO) models where PSO with R(2) = 0.999 best fitted the data, implying the predominant role of chemical adsorption in the dye removal process. Antibacterial tests revealed superior antibacterial activity of the prepared ZnS@GO@Pani NC against both Gram-negative and Gram-positive bacteria, demonstrating the remarkable synergistic effect of ZnS NPs embedded in the GO@Pani matrix. Accordingly, the prepared NC could be regarded as a promising candidate for wastewater treatment applications. The leaching and regeneration studies also confirmed that the prepared NC is a non-toxic dye removal agent with good reusability.
format Online
Article
Text
id pubmed-9134219
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-91342192022-06-21 Highly efficient, bioactive, and bifunctional sorbent p–n–p visible light heterogeneous photocatalyst utilizing ultra-fine ZnS nanoparticles embedded in a polymeric nanocomposite Bagheri, Hanieh Pasha, Mohammad Akbarzadeh Lakouraj, Moslem Mansour Hasantabar, Vahid Mohseni, Mojtaba RSC Adv Chemistry This study reports the successful synthesis of a ZnS@GO@Pani polymeric nanocomposite (NC) via chemical polymerization. The product was used for simultaneous photocatalytic degradation–adsorption of malachite green (MG), a carcinogenic and widely used dye. The physicochemical properties of the prepared NC were characterized by various techniques. Morphological and XRD results confirmed the fine size of ZnS nanoparticles (NPs) with an approximate mean size of 5 nm, uniformly distributed within the polymeric matrix. For comparative purposes, photocatalytic dye degradation–adsorption of this nanohybrid was explored both in the dark and under natural light. It was observed that 0.1 g of the ternary NC in MG aqueous solution (20 ppm) leads to dye adsorption within 15 minutes with an efficiency of 70% under dark conditions. Also, MG removal efficiency of up to 90% was achieved in 15 minutes under natural light owing to integrated photocatalytic degradation–adsorption mechanisms. Adsorption isotherm studies were performed considering Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich (D–R) models. The results showed that the Freundlich isotherm with R(2) = 0.988 is well consistent with the experimental data. Integrated photocatalytic degradation–adsorption kinetics were modeled with pseudo-first-order (PFO) and pseudo-second-order (PSO) models where PSO with R(2) = 0.999 best fitted the data, implying the predominant role of chemical adsorption in the dye removal process. Antibacterial tests revealed superior antibacterial activity of the prepared ZnS@GO@Pani NC against both Gram-negative and Gram-positive bacteria, demonstrating the remarkable synergistic effect of ZnS NPs embedded in the GO@Pani matrix. Accordingly, the prepared NC could be regarded as a promising candidate for wastewater treatment applications. The leaching and regeneration studies also confirmed that the prepared NC is a non-toxic dye removal agent with good reusability. The Royal Society of Chemistry 2022-05-26 /pmc/articles/PMC9134219/ /pubmed/35733686 http://dx.doi.org/10.1039/d2ra01810a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Bagheri, Hanieh
Pasha, Mohammad Akbarzadeh
Lakouraj, Moslem Mansour
Hasantabar, Vahid
Mohseni, Mojtaba
Highly efficient, bioactive, and bifunctional sorbent p–n–p visible light heterogeneous photocatalyst utilizing ultra-fine ZnS nanoparticles embedded in a polymeric nanocomposite
title Highly efficient, bioactive, and bifunctional sorbent p–n–p visible light heterogeneous photocatalyst utilizing ultra-fine ZnS nanoparticles embedded in a polymeric nanocomposite
title_full Highly efficient, bioactive, and bifunctional sorbent p–n–p visible light heterogeneous photocatalyst utilizing ultra-fine ZnS nanoparticles embedded in a polymeric nanocomposite
title_fullStr Highly efficient, bioactive, and bifunctional sorbent p–n–p visible light heterogeneous photocatalyst utilizing ultra-fine ZnS nanoparticles embedded in a polymeric nanocomposite
title_full_unstemmed Highly efficient, bioactive, and bifunctional sorbent p–n–p visible light heterogeneous photocatalyst utilizing ultra-fine ZnS nanoparticles embedded in a polymeric nanocomposite
title_short Highly efficient, bioactive, and bifunctional sorbent p–n–p visible light heterogeneous photocatalyst utilizing ultra-fine ZnS nanoparticles embedded in a polymeric nanocomposite
title_sort highly efficient, bioactive, and bifunctional sorbent p–n–p visible light heterogeneous photocatalyst utilizing ultra-fine zns nanoparticles embedded in a polymeric nanocomposite
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9134219/
https://www.ncbi.nlm.nih.gov/pubmed/35733686
http://dx.doi.org/10.1039/d2ra01810a
work_keys_str_mv AT bagherihanieh highlyefficientbioactiveandbifunctionalsorbentpnpvisiblelightheterogeneousphotocatalystutilizingultrafineznsnanoparticlesembeddedinapolymericnanocomposite
AT pashamohammadakbarzadeh highlyefficientbioactiveandbifunctionalsorbentpnpvisiblelightheterogeneousphotocatalystutilizingultrafineznsnanoparticlesembeddedinapolymericnanocomposite
AT lakourajmoslemmansour highlyefficientbioactiveandbifunctionalsorbentpnpvisiblelightheterogeneousphotocatalystutilizingultrafineznsnanoparticlesembeddedinapolymericnanocomposite
AT hasantabarvahid highlyefficientbioactiveandbifunctionalsorbentpnpvisiblelightheterogeneousphotocatalystutilizingultrafineznsnanoparticlesembeddedinapolymericnanocomposite
AT mohsenimojtaba highlyefficientbioactiveandbifunctionalsorbentpnpvisiblelightheterogeneousphotocatalystutilizingultrafineznsnanoparticlesembeddedinapolymericnanocomposite