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Synthesis of π-Extended Thiele’s and Chichibabin’s Hydrocarbons and Effect of the π-Congestion on Conformations and Electronic States

[Image: see text] The biradicaloid of Chichibabin’s hydrocarbon exits in a unique thermal equilibrium between closed-shell singlet and open-shell triplet forms. Conceptually, the incorporation of nonplanar aromatic groups, such as anthraquinodimethane (AQD), in these species could bring about stabil...

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Detalles Bibliográficos
Autores principales:	Nishiuchi, Tomohiko, Aibara, Seito, Sato, Hiroyasu, Kubo, Takashi
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9136924/ https://www.ncbi.nlm.nih.gov/pubmed/35426674 http://dx.doi.org/10.1021/jacs.2c02318

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