Stoichiometric Ratio Controlled Dimension Transition and Supramolecular Chirality Enhancement in a Two-Component Assembly System

To control the dimension of the supramolecular system was of great significance. We construct a two component self-assembly system, in which the gelator LHC18 and achiral azobenzene carboxylic acid could co-assembly and form gels. By modulating the stoichiometric ratio of the two components, not onl...

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Detalles Bibliográficos
Autores principales: Zhang, Penghui, Liu, Yiran, Fang, Xinkuo, Ma, Li, Wang, Yuanyuan, Ji, Lukang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9140661/
https://www.ncbi.nlm.nih.gov/pubmed/35621567
http://dx.doi.org/10.3390/gels8050269
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author Zhang, Penghui
Liu, Yiran
Fang, Xinkuo
Ma, Li
Wang, Yuanyuan
Ji, Lukang
author_facet Zhang, Penghui
Liu, Yiran
Fang, Xinkuo
Ma, Li
Wang, Yuanyuan
Ji, Lukang
author_sort Zhang, Penghui
collection PubMed
description To control the dimension of the supramolecular system was of great significance. We construct a two component self-assembly system, in which the gelator LHC18 and achiral azobenzene carboxylic acid could co-assembly and form gels. By modulating the stoichiometric ratio of the two components, not only the morphology could be transformed from 1D nanaotube to 0D nanospheres but also the supramolecualr chirality could be tuned. This work could provide some insights to the control of dimension and the supramolecular chirality in the two-component systems by simply modulating the stoichiometric ratio.
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spelling pubmed-91406612022-05-28 Stoichiometric Ratio Controlled Dimension Transition and Supramolecular Chirality Enhancement in a Two-Component Assembly System Zhang, Penghui Liu, Yiran Fang, Xinkuo Ma, Li Wang, Yuanyuan Ji, Lukang Gels Communication To control the dimension of the supramolecular system was of great significance. We construct a two component self-assembly system, in which the gelator LHC18 and achiral azobenzene carboxylic acid could co-assembly and form gels. By modulating the stoichiometric ratio of the two components, not only the morphology could be transformed from 1D nanaotube to 0D nanospheres but also the supramolecualr chirality could be tuned. This work could provide some insights to the control of dimension and the supramolecular chirality in the two-component systems by simply modulating the stoichiometric ratio. MDPI 2022-04-26 /pmc/articles/PMC9140661/ /pubmed/35621567 http://dx.doi.org/10.3390/gels8050269 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Zhang, Penghui
Liu, Yiran
Fang, Xinkuo
Ma, Li
Wang, Yuanyuan
Ji, Lukang
Stoichiometric Ratio Controlled Dimension Transition and Supramolecular Chirality Enhancement in a Two-Component Assembly System
title Stoichiometric Ratio Controlled Dimension Transition and Supramolecular Chirality Enhancement in a Two-Component Assembly System
title_full Stoichiometric Ratio Controlled Dimension Transition and Supramolecular Chirality Enhancement in a Two-Component Assembly System
title_fullStr Stoichiometric Ratio Controlled Dimension Transition and Supramolecular Chirality Enhancement in a Two-Component Assembly System
title_full_unstemmed Stoichiometric Ratio Controlled Dimension Transition and Supramolecular Chirality Enhancement in a Two-Component Assembly System
title_short Stoichiometric Ratio Controlled Dimension Transition and Supramolecular Chirality Enhancement in a Two-Component Assembly System
title_sort stoichiometric ratio controlled dimension transition and supramolecular chirality enhancement in a two-component assembly system
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9140661/
https://www.ncbi.nlm.nih.gov/pubmed/35621567
http://dx.doi.org/10.3390/gels8050269
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