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Comparison of Effects of Different Sacrificial Hydrogen Bonds on Performance of Polyurethane/Graphene Oxide Membrane
Processing robust mechanical properties is important for elastomeric materials. In this work, different molecular weights of polyethylene glycols (PEG) were used to modify graphene oxide (GO) in order to study the relationship between the number of hydrogen bonds and the properties of the polyuretha...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9144129/ https://www.ncbi.nlm.nih.gov/pubmed/35629843 http://dx.doi.org/10.3390/membranes12050517 |
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author | Fu, Wen Wang, Li Huang, Zhuohang Huang, Xiaoyan Su, Zhijin Liang, Yixing Gao, Zhitin Pan, Qingyu |
author_facet | Fu, Wen Wang, Li Huang, Zhuohang Huang, Xiaoyan Su, Zhijin Liang, Yixing Gao, Zhitin Pan, Qingyu |
author_sort | Fu, Wen |
collection | PubMed |
description | Processing robust mechanical properties is important for elastomeric materials. In this work, different molecular weights of polyethylene glycols (PEG) were used to modify graphene oxide (GO) in order to study the relationship between the number of hydrogen bonds and the properties of the polyurethane/graphene oxide membrane. The fact of PEG was successfully grafted onto the surface of GO was certified by Fourier transform infrared spectra, Raman spectra, X-ray photoelectron spectroscopy. The graft ratio was indicated by thermogravimetric analysis. The presence of hydrogen bonds in PUR/MGO composites membrane was proved by the cyclic loading-unloading test and stress relaxation test. The thermal stability and low-temperature resistance performance of PUR/MGO had been improved compared with PUR/GO. When the molecular weight of PEG grafted on the surface of GO was 600, the tensile strength and elongation at break of the composite membrane were optimal. The reason for the improvement of physical and mechanical properties was that the dispersion of filler in the rubber matrix and the compatibility between filler and rubber had been improved. |
format | Online Article Text |
id | pubmed-9144129 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-91441292022-05-29 Comparison of Effects of Different Sacrificial Hydrogen Bonds on Performance of Polyurethane/Graphene Oxide Membrane Fu, Wen Wang, Li Huang, Zhuohang Huang, Xiaoyan Su, Zhijin Liang, Yixing Gao, Zhitin Pan, Qingyu Membranes (Basel) Article Processing robust mechanical properties is important for elastomeric materials. In this work, different molecular weights of polyethylene glycols (PEG) were used to modify graphene oxide (GO) in order to study the relationship between the number of hydrogen bonds and the properties of the polyurethane/graphene oxide membrane. The fact of PEG was successfully grafted onto the surface of GO was certified by Fourier transform infrared spectra, Raman spectra, X-ray photoelectron spectroscopy. The graft ratio was indicated by thermogravimetric analysis. The presence of hydrogen bonds in PUR/MGO composites membrane was proved by the cyclic loading-unloading test and stress relaxation test. The thermal stability and low-temperature resistance performance of PUR/MGO had been improved compared with PUR/GO. When the molecular weight of PEG grafted on the surface of GO was 600, the tensile strength and elongation at break of the composite membrane were optimal. The reason for the improvement of physical and mechanical properties was that the dispersion of filler in the rubber matrix and the compatibility between filler and rubber had been improved. MDPI 2022-05-13 /pmc/articles/PMC9144129/ /pubmed/35629843 http://dx.doi.org/10.3390/membranes12050517 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Fu, Wen Wang, Li Huang, Zhuohang Huang, Xiaoyan Su, Zhijin Liang, Yixing Gao, Zhitin Pan, Qingyu Comparison of Effects of Different Sacrificial Hydrogen Bonds on Performance of Polyurethane/Graphene Oxide Membrane |
title | Comparison of Effects of Different Sacrificial Hydrogen Bonds on Performance of Polyurethane/Graphene Oxide Membrane |
title_full | Comparison of Effects of Different Sacrificial Hydrogen Bonds on Performance of Polyurethane/Graphene Oxide Membrane |
title_fullStr | Comparison of Effects of Different Sacrificial Hydrogen Bonds on Performance of Polyurethane/Graphene Oxide Membrane |
title_full_unstemmed | Comparison of Effects of Different Sacrificial Hydrogen Bonds on Performance of Polyurethane/Graphene Oxide Membrane |
title_short | Comparison of Effects of Different Sacrificial Hydrogen Bonds on Performance of Polyurethane/Graphene Oxide Membrane |
title_sort | comparison of effects of different sacrificial hydrogen bonds on performance of polyurethane/graphene oxide membrane |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9144129/ https://www.ncbi.nlm.nih.gov/pubmed/35629843 http://dx.doi.org/10.3390/membranes12050517 |
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